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- W2073236416 abstract "Abstract Ethyl(dimethoxy)borane is prepared by a two‐step method involving reaction of triethylboroxin with 1,4‐butanediol in a molar ratio of 1:3 to give oligomeric 1,4‐butanediyldioxy‐ethylboranes which are then treated with methanol. D ‐Lyxose ( 1 ) reacts selectively with ethyl(dimethoxy)borane in the presence of acidic ion exchange resin to form methyl 2,3‐ O ‐ethylboranediyl‐α‐ D ‐lyxofuranoside ( 2 ) which is deboronated to give methyl α‐ D ‐lyxofuranoside ( 4 ). Similarly, D ‐mannose ( 6 ) reacts to give methyl 2,3:5,6‐bis‐ O ‐ethylboranediyl‐α‐ D ‐mannofuranoside ( 7 ), the deprotection of which yields methyl α‐ D ‐mannofuranoside ( 8 )." @default.
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- W2073236416 date "1990-08-13" @default.
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- W2073236416 title "Organoboron monosaccharides, XVI. Selective syntheses of the methyl α-D-furanosides of Lyxose and Mannose using ethyl(dimethoxy)borane" @default.
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- W2073236416 doi "https://doi.org/10.1002/jlac.1990199001149" @default.
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