FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073246206> ?p ?o ?g. }

• W2073246206 endingPage "1128" @default.
• W2073246206 startingPage "1121" @default.
• W2073246206 abstract "A modified Freeman–Murray–Richards (FMR) correlation for the analysis of 59Co NMR shielding parameters, δ(59Co)vs.(Δv*1/2)1/2/ΔEav, is formulated by combining the Ramsey shielding theory and the Townes and Dailey theory for the calculation of the nuclear quadrupole coupling constant. It is demonstrated that the experimental 59Co NMR half-height linewidth is a useful parameter to account for the nephelauxetic effect in the shielding variation in CoIII complexes. The correlation shows that the differences in the cobalt chemical shifts are characteristic of the hardness or softness of the metal–ligand interaction. While Bramley and Juranić modified the FMR plot by introducing a second optical parameter, β35, to account for the nephelauxetic effect, we invoke the quadrupolar metal NMR linewidth to achieve the same degree of modification. This treatment provides a practical means of separating the spectrochemical effect from the nephelauxetic effect. The former is shown to span a range of ca. 3500 ppm and the latter ca. 800–1200 ppm covering the complexes in the series [Co(NH3)5X](3 +n)+, [Co(CN)5X](2 –n)– and trans-[Co(en)2X2](3 + 2n)+. In total, the 59Co NMR data of 37 diamagnetic hexacoordinated CoIII complexes in five different solvents are analysed. The model is verified independently using complexes from the series trans-[Co(acac)2X2](1 + 2n)± as well as trans-[Co(acac)2(NH3)(NO2)]." @default.
• W2073246206 created "2016-06-24" @default.
• W2073246206 creator A5019942955 @default.
• W2073246206 creator A5056774530 @default.
• W2073246206 date "1996-01-01" @default.
• W2073246206 modified "2023-09-27" @default.
• W2073246206 title "Interpretation of⁵⁹Co NMR shielding using the hard and soft acid–base concept. Insight into the relative magnitude of the nephelauxetic and the spectrochemical effect" @default.
• W2073246206 cites W1598334653 @default.
• W2073246206 cites W1661863349 @default.
• W2073246206 cites W1967156362 @default.
• W2073246206 cites W1968684993 @default.
• W2073246206 cites W1968953483 @default.
• W2073246206 cites W1969897490 @default.
• W2073246206 cites W1971529951 @default.
• W2073246206 cites W1991061109 @default.
• W2073246206 cites W1997239149 @default.
• W2073246206 cites W2005877813 @default.
• W2073246206 cites W2009218859 @default.
• W2073246206 cites W2012130053 @default.
• W2073246206 cites W2014338134 @default.
• W2073246206 cites W2017086725 @default.
• W2073246206 cites W2017580784 @default.
• W2073246206 cites W2020339643 @default.
• W2073246206 cites W2021494982 @default.
• W2073246206 cites W2021807023 @default.
• W2073246206 cites W2023381900 @default.
• W2073246206 cites W2029414700 @default.
• W2073246206 cites W2033844788 @default.
• W2073246206 cites W2041690243 @default.
• W2073246206 cites W2045180847 @default.
• W2073246206 cites W2047845763 @default.
• W2073246206 cites W2068559689 @default.
• W2073246206 cites W2068991420 @default.
• W2073246206 cites W2076937299 @default.
• W2073246206 cites W2079312975 @default.
• W2073246206 cites W2080357481 @default.
• W2073246206 cites W2084127384 @default.
• W2073246206 cites W2084660168 @default.
• W2073246206 cites W2089439412 @default.
• W2073246206 cites W2092791697 @default.
• W2073246206 cites W2121204128 @default.
• W2073246206 cites W2327222076 @default.
• W2073246206 cites W2950234228 @default.
• W2073246206 cites W3004781078 @default.
• W2073246206 cites W3004876795 @default.
• W2073246206 cites W3139279814 @default.
• W2073246206 doi "https://doi.org/10.1039/ft9969201121" @default.
• W2073246206 hasPublicationYear "1996" @default.
• W2073246206 type Work @default.
• W2073246206 sameAs 2073246206 @default.
• W2073246206 citedByCount "15" @default.
• W2073246206 countsByYear W20732462062015 @default.
• W2073246206 countsByYear W20732462062017 @default.
• W2073246206 countsByYear W20732462062023 @default.
• W2073246206 crossrefType "journal-article" @default.
• W2073246206 hasAuthorship W2073246206A5019942955 @default.
• W2073246206 hasAuthorship W2073246206A5056774530 @default.
• W2073246206 hasConcept C111429119 @default.
• W2073246206 hasConcept C113196181 @default.
• W2073246206 hasConcept C115260700 @default.
• W2073246206 hasConcept C116569031 @default.
• W2073246206 hasConcept C121332964 @default.
• W2073246206 hasConcept C142181693 @default.
• W2073246206 hasConcept C147789679 @default.
• W2073246206 hasConcept C170493617 @default.
• W2073246206 hasConcept C178790620 @default.
• W2073246206 hasConcept C179104552 @default.
• W2073246206 hasConcept C183276030 @default.
• W2073246206 hasConcept C184779094 @default.
• W2073246206 hasConcept C185592680 @default.
• W2073246206 hasConcept C2265751 @default.
• W2073246206 hasConcept C39984356 @default.
• W2073246206 hasConcept C43617362 @default.
• W2073246206 hasConcept C515602321 @default.
• W2073246206 hasConcept C520434653 @default.
• W2073246206 hasConcept C544153396 @default.
• W2073246206 hasConcept C55493867 @default.
• W2073246206 hasConcept C62520636 @default.
• W2073246206 hasConcept C96026104 @default.
• W2073246206 hasConceptScore W2073246206C111429119 @default.
• W2073246206 hasConceptScore W2073246206C113196181 @default.
• W2073246206 hasConceptScore W2073246206C115260700 @default.
• W2073246206 hasConceptScore W2073246206C116569031 @default.
• W2073246206 hasConceptScore W2073246206C121332964 @default.
• W2073246206 hasConceptScore W2073246206C142181693 @default.
• W2073246206 hasConceptScore W2073246206C147789679 @default.
• W2073246206 hasConceptScore W2073246206C170493617 @default.
• W2073246206 hasConceptScore W2073246206C178790620 @default.
• W2073246206 hasConceptScore W2073246206C179104552 @default.
• W2073246206 hasConceptScore W2073246206C183276030 @default.
• W2073246206 hasConceptScore W2073246206C184779094 @default.
• W2073246206 hasConceptScore W2073246206C185592680 @default.
• W2073246206 hasConceptScore W2073246206C2265751 @default.
• W2073246206 hasConceptScore W2073246206C39984356 @default.
• W2073246206 hasConceptScore W2073246206C43617362 @default.
• W2073246206 hasConceptScore W2073246206C515602321 @default.
• W2073246206 hasConceptScore W2073246206C520434653 @default.
• W2073246206 hasConceptScore W2073246206C544153396 @default.

• next