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- W2073246290 abstract "Partitioning of 15 volatile organic compounds (VOCs) between the vapor phase and dry and moist Al2O3 samples was measured using a headspace technique. The best predictors of partition coefficients (K′p) from the vapor phase varied with the three Al2O3 moisture contents (MCs) used; these variations may reflect alternate sorption mechanisms. For instance, sorption of chlorinated hydrocarbons at 1.9% MC was best explained by the hydrogen bond acceptor parameter β, suggesting hydrogen bonding between the —Cl group and surface groups or water films. However, sorption on humic acid-coated Al2O3 at approximately 45% MC was best explained by the log of the aqueous solubility and Henry's law constant. The importance of aqueous solubility and Henry's law constant suggested that dissolution of organic compounds in interstitial water is a primary sorption mechanism for VOCs at high Al2O3 MCs. Sorption of the relatively insoluble hydrocarbons such as n-alkanes occurred in excess of that explained by dissolution in the interstitial water and may reflect the importance of partitioning into the organic matter provided by the humic acid coating." @default.
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- W2073246290 date "1992-10-01" @default.
- W2073246290 modified "2023-09-25" @default.
- W2073246290 title "Vapor-phase partitioning of volatile organic compounds: A regression approach" @default.
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- W2073246290 doi "https://doi.org/10.1002/etc.5620111004" @default.
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