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• W2073254237 endingPage "74" @default.
• W2073254237 startingPage "65" @default.
• W2073254237 abstract "Abstract The ability of three center chelating ligands to form dichromium units and to enforce short and very short CrCr contacts is examined in a consistent series of cyclohexyl amidinate chromium complexes, with the aim of understanding the factors intrinsic in the nature of the bridging ligands which are able to promote or disfavor dinuclear aggregation and to determine the extent of intermetallic separation. The present study describing the crystal structures of the dinuclear [(CyNC(H)NCy)2Cr]2·C7H8 (1) and mononuclear (CyNC(CH3)NCy)2Cr (2), {CyNC[Ph(o-CH2NMe2)]NCy}2Cr·2THF (3) and [(Me3Si)NC(Ph)N(SiMe3)]2Cr (4) indicates that the steric interaction between the lateral cyclohexyl and the central amidinate group is capable of determining the nuclearity (monomeric versus dimeric) and probably the extent of intermetallic separation. Crystal data are as follows. 1: C52H84N8Cr2·toluene, M=1017.41, monoclinic, P21/c, a=13.682(5), b=17.446(3), c=24.521(3) A, β=90.02(5)°, V=5853(3) A3, Z=4, T=−30 °C, Mo Kα, R=0.104, Rw=0.077 for 4030 reflections out of 10319 unique; 2: C28H50N4Cr, M=494.73, orthorhombic, Pnma, a=8.104(1), b=26.572(4), c=12.533(2) A, V=2699(1) A3, Z=4, T=−157 °C, Mo Kα, R=0.054, Rw=0.069 for 1580 reflections out of 2752 unique; 3: C44H68N6Cr·2THF, M=853.16, triclinic, P 1 , a=12.293(5), b=20.437(5), c=11.071(4) A, α=94.55(3), β=111.72(3), γ=73.86(3)°, V=2481(1) A3, Z=2, T=−157 °C, Mo Kα, R=0.093, Rw=0.081 for 6492 reflections out of 8710 unique." @default.
• W2073254237 created "2016-06-24" @default.
• W2073254237 creator A5051790115 @default.
• W2073254237 creator A5063225492 @default.
• W2073254237 creator A5063317439 @default.
• W2073254237 creator A5089784885 @default.
• W2073254237 date "1993-11-01" @default.
• W2073254237 modified "2023-09-26" @default.
• W2073254237 title "Ligand steric bulk: A neglected factor in the formation of CrCr supershort contacts" @default.
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• W2073254237 cites W1966342029 @default.
• W2073254237 cites W1971143860 @default.
• W2073254237 cites W1971920214 @default.
• W2073254237 cites W1974239612 @default.
• W2073254237 cites W1976104981 @default.
• W2073254237 cites W1980836224 @default.
• W2073254237 cites W1982881636 @default.
• W2073254237 cites W1986475187 @default.
• W2073254237 cites W1991074080 @default.
• W2073254237 cites W1991582064 @default.
• W2073254237 cites W1992117018 @default.
• W2073254237 cites W1994763691 @default.
• W2073254237 cites W1996663508 @default.
• W2073254237 cites W1997362453 @default.
• W2073254237 cites W2001179041 @default.
• W2073254237 cites W2002923171 @default.
• W2073254237 cites W2003205139 @default.
• W2073254237 cites W2004997155 @default.
• W2073254237 cites W2007444175 @default.
• W2073254237 cites W2008397329 @default.
• W2073254237 cites W2010008177 @default.
• W2073254237 cites W2020247738 @default.
• W2073254237 cites W2021323577 @default.
• W2073254237 cites W2022539746 @default.
• W2073254237 cites W2023215297 @default.
• W2073254237 cites W2024284581 @default.
• W2073254237 cites W2036888150 @default.
• W2073254237 cites W2039652522 @default.
• W2073254237 cites W2040789640 @default.
• W2073254237 cites W2042901924 @default.
• W2073254237 cites W2044110348 @default.
• W2073254237 cites W2044400276 @default.
• W2073254237 cites W2045226245 @default.
• W2073254237 cites W2049643120 @default.
• W2073254237 cites W2050390446 @default.
• W2073254237 cites W2050905799 @default.
• W2073254237 cites W2056426392 @default.
• W2073254237 cites W2057664918 @default.
• W2073254237 cites W2058205547 @default.
• W2073254237 cites W2061858561 @default.
• W2073254237 cites W2062224143 @default.
• W2073254237 cites W2070387402 @default.
• W2073254237 cites W2072231619 @default.
• W2073254237 cites W2073046120 @default.
• W2073254237 cites W2074863052 @default.
• W2073254237 cites W2075618574 @default.
• W2073254237 cites W2075618805 @default.
• W2073254237 cites W2081192606 @default.
• W2073254237 cites W2081223527 @default.
• W2073254237 cites W2081850916 @default.
• W2073254237 cites W2083620759 @default.
• W2073254237 cites W2083993046 @default.
• W2073254237 cites W2084057147 @default.
• W2073254237 cites W2087167152 @default.
• W2073254237 cites W2090203452 @default.
• W2073254237 cites W2091015491 @default.
• W2073254237 cites W2092091813 @default.
• W2073254237 cites W2093897688 @default.
• W2073254237 cites W2097346376 @default.
• W2073254237 cites W2120340323 @default.
• W2073254237 cites W2135203768 @default.
• W2073254237 cites W2140648759 @default.
• W2073254237 cites W2149236734 @default.
• W2073254237 cites W2157833425 @default.
• W2073254237 cites W2182586543 @default.
• W2073254237 cites W2314089643 @default.
• W2073254237 cites W2319080572 @default.
• W2073254237 cites W2343810949 @default.
• W2073254237 cites W2464100734 @default.
• W2073254237 cites W2497208890 @default.
• W2073254237 cites W2746385086 @default.
• W2073254237 cites W2949709605 @default.
• W2073254237 cites W2949804746 @default.
• W2073254237 cites W2952047214 @default.
• W2073254237 cites W2952743819 @default.
• W2073254237 cites W2952994830 @default.
• W2073254237 cites W2953059599 @default.
• W2073254237 cites W3005031255 @default.
• W2073254237 cites W3139406841 @default.
• W2073254237 cites W4240660347 @default.
• W2073254237 doi "https://doi.org/10.1016/s0020-1693(00)83815-3" @default.
• W2073254237 hasPublicationYear "1993" @default.
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