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- W2073258688 abstract "Crystals of the so-called blue bronze Tl0.30MoO3 were prepared by tempering molten mixtures. The structure was refined in the space group C2/m from 2171 reflections corrected for absorption. The R and Rw factors obtained from the last refinement cycle are 0.030 and 0.036 respectively for 114 refined parameters. The Zachariasen method enabled the 4d distribution over the three independent sites Mo1, Mo2 and Mo3 to be determined and gave 16.6 %, 39.7 % and 43.7 % respectively. For each octahedron a close correlation appears between the number of shared edges, the formal molybdenum charge and its eccentricity within the polyhedron. It is found that the molybdenum Mo1 has the highest formal charge ; this site does not seem to participate in the electrical conductivity which takes place mainly in the slabs thanks to the molybdenum sites Mo2 and Mo3 which represent 83.4 % of the electron density. Tl0.30MoO3 shows a metal-to-semiconductor transition at 185 K, probably of Peierls type. We propose that the non-linear effects and metastability phenomena observed below 180 K, in the non-ohmic regime are very likely due to the depinning of a charge density wave, as it has been found in the blue bronze K0.30MoO3" @default.
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- W2073258688 date "1985-11-01" @default.
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- W2073258688 title "The blue bronze Tl0.30MoO3 structure and physical properties" @default.
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- W2073258688 doi "https://doi.org/10.1016/0025-5408(85)90124-2" @default.
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