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• W2073258796 startingPage "2259" @default.
• W2073258796 abstract "The sodium amalgam reduction (2 Na per W) of hydrocarbon solutions of [W(OC6HPh4-2,3,5,6)2Cl4] in the presence of pyridine or 4-tert-butylpyridine leads to the W(IV) compounds [W(OC6HPh4-2,3,5,6)2Cl2(py)2] (1) and [W(OC6HPh4-2,3,5,6)2Cl2(4-tert-butylpyridine)2] (2) in good yields. The ambient-temperature 1H NMR spectra of both 1 and 2 were found to be sharp and to exhibit extensive contact shifts due to the paramagnetic tungsten center. The addition of 2,2‘-bipyridine to an emerald green solution of [W(OC6HPh3-η6-C6H5)(OC6HPh4-2,3,5,6)(PEt3)] produced [W(OC6HPh4-2,3,5,6)2(bipy)2] (3), containing two bipy rings and two terminal aryloxide ligands coordinated mutually cis. The W−N(bipy) distances of 2.092(2), 2.093(2), 2.096(2), and 2.115(2) A in 3 are among the shortest so far reported for bipy ligands bound to either molybdenum or tungsten. The solid state and solution data for 3 indicate that reduction of both bipy ligands has occurred, but whether this involves four-electron reduction to yield d0-W(VI) i..." @default.
• W2073258796 created "2016-06-24" @default.
• W2073258796 creator A5007060871 @default.
• W2073258796 creator A5057330382 @default.
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• W2073258796 date "2003-05-01" @default.
• W2073258796 modified "2023-09-26" @default.
• W2073258796 title "Low-Valent Tungsten Aryloxide Compounds with Pyridine Ancillary Ligation: Intramolecular Reduction of Heterocyclic and Aromatic Rings Including Formation of an η⁵-Cyclohexadienyl Group" @default.
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• W2073258796 doi "https://doi.org/10.1021/om030054s" @default.
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