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- W2073263306 abstract "The value of the carbonyl-stretching frequency in molecules of the type COXY is determined not only by the CO force constant, but also by the masses of X and Y, the molecular configuration, and the remaining force constants. A numerical analysis of the dependence of νco on these factors allows us to estimate a correction to the observed carbonyl frequency which takes into account these extraneous effects and leads to a frequency νco∗ which truly reflects the strength of the CO bond. In the acetyl, carbonyl and benzoyl halides the value of νco∗ has been found to be almost independent of the nature of the halogen substituent." @default.
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- W2073263306 date "1960-01-01" @default.
- W2073263306 modified "2023-09-28" @default.
- W2073263306 title "The contributions of mass and force-constant effects to the carbonyl-stretching frequency of acetyl, carbonyl and benzoyl halides" @default.
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- W2073263306 doi "https://doi.org/10.1016/0371-1951(60)80023-9" @default.
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