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- W2073283665 abstract "We report herein a novel Ruthenium bipyridyl-Nafion-ormosil composite material cast onto an ITO electrode and used for electrochemiluminescent (ECL) detection of dopamine. The modified electrodes are made using the homogeneous solution of [Ru(bpy) <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>3</sub> ] <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2+</sup> , Nafion <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>®</sup> 117 and 3-glycidoxypropyltrimethoxysilane. The encapsulated [Ru(bpy) <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>3</sub> ] <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2+</sup> showed catalyzed ECL response as compared to that of plain [Ru(bpy) <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>3</sub> ] <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2+</sup> -Nafion matrix. The new composite material (Rusystem) was further modulated by the introduction of gold nanoparticles within composite matrix. Quantitative relation between catalytic efficiency of [Ru(bpy) <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>3</sub> ] <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2+</sup> and ECL yield has been recorded. The lowest detection limit of dopamine analysis was found to be < 0.1 ¿M." @default.
- W2073283665 created "2016-06-24" @default.
- W2073283665 creator A5004790787 @default.
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- W2073283665 date "2009-10-01" @default.
- W2073283665 modified "2023-09-23" @default.
- W2073283665 title "Application of tris(2-2'-bipyridyl)ruthenium(II)-Nafion-ormosil-modified electrode in selective sensing of dopamine" @default.
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- W2073283665 doi "https://doi.org/10.1109/icsens.2009.5398577" @default.
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