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- W2073283695 abstract "A nonsymmetric phosphorus ylide and its palladium(II) complex have been synthesized as potential catalytically active compounds. The reaction of 1 equiv nonsymmetric phosphorus ylide, Ph2PCH2PPh2C(H)C(O)PhBr with [Pd(dppe)Cl2], followed by treatment with 2 equiv AgOTf led to [(dppe)Pd(Ph2PCH2PPh2C(H)C(O)PhBr)](OSO2CF3)2, which contains a five-membered P,P chelate ring on one side and a five-membered P,C chelate ring on the other side. The palladium complex was synthesized and investigated by fourier transform infrared spectroscopy (FT-IR), UV–visible, multinuclear (1H, 31P and 19F) nuclear magnetic resonance (NMR), and electrospray ionisation-mass spectroscopic techniques. FT-IR and 31P NMR studies revealed that the phosphorus ylide is coordinated to palladium via the terminal phosphorus (Pc) of the ylide and methene group (CH). Suzuki reactions for varying aryl halides using the cyclopalladated complex as an efficient catalyst were performed. Various aryl halides were coupled with arylboronic acids in DMF, under air, in the presence of 0.001 mol% of the homogeneous catalyst to afford the corresponding cross-coupled products in good to excellent yields." @default.
- W2073283695 created "2016-06-24" @default.
- W2073283695 creator A5038328938 @default.
- W2073283695 creator A5059700167 @default.
- W2073283695 creator A5066816471 @default.
- W2073283695 date "2013-01-29" @default.
- W2073283695 modified "2023-10-18" @default.
- W2073283695 title "Five-membered cyclopalladated complex containing bidentate phosphine ligands; Synthesis, characterization, and highly efficient Suzuki cross-coupling reactions" @default.
- W2073283695 cites W1561311795 @default.
- W2073283695 cites W1964190557 @default.
- W2073283695 cites W1965042700 @default.
- W2073283695 cites W1970369808 @default.
- W2073283695 cites W1970460359 @default.
- W2073283695 cites W1970800627 @default.
- W2073283695 cites W1972982925 @default.
- W2073283695 cites W1973051136 @default.
- W2073283695 cites W1973117152 @default.
- W2073283695 cites W1973786313 @default.
- W2073283695 cites W1974909313 @default.
- W2073283695 cites W1978890358 @default.
- W2073283695 cites W1979699202 @default.
- W2073283695 cites W1979971049 @default.
- W2073283695 cites W1981754097 @default.
- W2073283695 cites W1982060766 @default.
- W2073283695 cites W1982470390 @default.
- W2073283695 cites W1983663908 @default.
- W2073283695 cites W1985042246 @default.
- W2073283695 cites W1986858488 @default.
- W2073283695 cites W1988964848 @default.
- W2073283695 cites W1989558366 @default.
- W2073283695 cites W1990484521 @default.
- W2073283695 cites W1992899849 @default.
- W2073283695 cites W1995407939 @default.
- W2073283695 cites W1995776320 @default.
- W2073283695 cites W1996742069 @default.
- W2073283695 cites W1997228274 @default.
- W2073283695 cites W2002858439 @default.
- W2073283695 cites W2004867175 @default.
- W2073283695 cites W2007014213 @default.
- W2073283695 cites W2016281653 @default.
- W2073283695 cites W2020419388 @default.
- W2073283695 cites W2020876023 @default.
- W2073283695 cites W2026424426 @default.
- W2073283695 cites W2029874190 @default.
- W2073283695 cites W2032622073 @default.
- W2073283695 cites W2033605088 @default.
- W2073283695 cites W2034745592 @default.
- W2073283695 cites W2036116184 @default.
- W2073283695 cites W2047001506 @default.
- W2073283695 cites W2050964393 @default.
- W2073283695 cites W2053177042 @default.
- W2073283695 cites W2054652820 @default.
- W2073283695 cites W2062756539 @default.
- W2073283695 cites W2063205667 @default.
- W2073283695 cites W2066327117 @default.
- W2073283695 cites W2067459099 @default.
- W2073283695 cites W2072150976 @default.
- W2073283695 cites W2073387777 @default.
- W2073283695 cites W2075537152 @default.
- W2073283695 cites W2079805975 @default.
- W2073283695 cites W2081964594 @default.
- W2073283695 cites W2085978059 @default.
- W2073283695 cites W2090033165 @default.
- W2073283695 cites W2090930067 @default.
- W2073283695 cites W2114453576 @default.
- W2073283695 cites W2121592937 @default.
- W2073283695 cites W2124954653 @default.
- W2073283695 cites W2133515826 @default.
- W2073283695 cites W2133703386 @default.
- W2073283695 cites W2141453896 @default.
- W2073283695 cites W2143856302 @default.
- W2073283695 cites W2145238250 @default.
- W2073283695 cites W2153587535 @default.
- W2073283695 cites W2161550840 @default.
- W2073283695 cites W2163083037 @default.
- W2073283695 cites W2164930732 @default.
- W2073283695 cites W2167677694 @default.
- W2073283695 cites W2949584603 @default.
- W2073283695 cites W2949739759 @default.
- W2073283695 cites W2950570862 @default.
- W2073283695 cites W2950735959 @default.
- W2073283695 cites W2950744328 @default.
- W2073283695 cites W2950828634 @default.
- W2073283695 cites W2951264427 @default.
- W2073283695 cites W4237461109 @default.
- W2073283695 cites W4255733708 @default.
- W2073283695 cites W426754412 @default.
- W2073283695 cites W2022313396 @default.
- W2073283695 doi "https://doi.org/10.1080/00958972.2012.759216" @default.
- W2073283695 hasPublicationYear "2013" @default.
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