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• W2073304826 startingPage "627" @default.
• W2073304826 abstract "The small-signal impedance of chemical cells with ``blocking'' electrodes is dominated at low frequencies (f<ensuremath{sim}100 Hz) by the impedance of the metal-electrolyte interfaces which is accurately represented by ${mathrm{Z}}_{mathrm{i}}$=A(jensuremath{omega}${)}^{mathrm{ensuremath{-}}mathrm{n}}$. The frequency exponent n, n<1, is sensitive to the texture of the interface, and several recent theories have been proposed that relate n with the fractal dimension difmmodebarelsetextasciimacronfi{} of the rough interface. We find no correlation between n and difmmodebarelsetextasciimacronfi{} from experiments using aqueous electrolytes and metal and semiconductor electrodes." @default.
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• W2073304826 date "1988-02-15" @default.
• W2073304826 modified "2023-10-05" @default.
• W2073304826 title "Surface topography and impedance of metal-electrolyte interfaces" @default.
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• W2073304826 doi "https://doi.org/10.1103/physrevlett.60.627" @default.
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