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- W2073306999 abstract "Arrhenius parameters have been determined for the hydrogen-abstraction reactions: R + SiHCl3 + RH + SiCl3 R Temp (°K) E(kcal/mole) Log A(mole−1 cc sec−1) Log k(400°K) (mole−1 cc sec−1) CF3 323–461 5.98 ± 0.06 11.77 ± 0.03 8.50 CH3 333–443 4.30 ± 0.08 10.83 ± 0.04 4.48 C2H5 314–413 5.32 ± 0.07 11.54 ± 0.04 8.63 The trend in activation energies E < E < E is interpreted as indicating a polar effect in the reaction of CF3 with SiHCl3 and the similar reactivities of all three radicals appear to be due to the high exothermicity of the reactions. The A Factors for the reactions are normal for hydrogen abstraction reactions of free radicals. The previous results of Kerr, Slater, and Young for CH3 abstracting an H atom from SiHCl3 have been amended." @default.
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- W2073306999 date "1969-07-01" @default.
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- W2073306999 title "Hydrogen abstraction reactions from organosilicon compounds. The reactions of methyl, trifluoromethyl, and ethyl radicals with trichlorosilane" @default.
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- W2073306999 doi "https://doi.org/10.1002/kin.550010403" @default.
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