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• W2073307510 abstract "Ternary intermetallic compounds, which possess a wide variety of important properties with both academic and technological relevance, are typically synthesized using traditional high-temperature methods. Here, we demonstrate that the polyol method, which is used extensively to synthesize nanocrystals and nanocrystalline powders of metals and simple binary compounds, serves as an effective low-temperature exploratory medium for synthesizing new ordered ternary intermetallics as nanocrystals. Accordingly, we describe the synthesis and structural characterization of AuCuSn2 and AuNiSn2, which adopt an ordered NiAs-type superstructure that is not observed using equilibrium synthetic methods. AuCuSn2 forms in solution of 120 °C as well-formed nanocrystals, and the ordered phase is stable up to 450 °C. AuNiSn2 behaves similarly to AuCuSn2." @default.
• W2073307510 created "2016-06-24" @default.
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• W2073307510 date "2005-05-03" @default.
• W2073307510 modified "2023-10-03" @default.
• W2073307510 title "Low-Temperature Polyol Synthesis of AuCuSn₂ and AuNiSn₂: Using Solution Chemistry to Access Ternary Intermetallic Compounds as Nanocrystals" @default.
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• W2073307510 doi "https://doi.org/10.1021/ja051481v" @default.
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