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- W2073312954 abstract "Single crystals of the endohedral $mathrm{La}@{mathrm{C}}_{82}({mathrm{CS}}_{2}{)}_{1.5}$ have been investigated by ESR, SQUID, and optical absorption measurements. We find that the crystal is a localized paramagnet at room temperature with evidence of strong antiferromagnetic interactions $(ensuremath{theta}ensuremath{sim}ensuremath{-}130 mathrm{K}).$ ESR spectroscopy reveals evidence of a phase transition at 150 K, that we assign to be an orientational ordering transition of the fullerene molecules. Furthermore, at low temperatures we find a magnetic bistability that can be controlled by the cooling rate. Investigations of $mathrm{Ce}@{mathrm{C}}_{82}({mathrm{CS}}_{2}{)}_{1.5}$ reveal evidence of similar bistability and hence we postulate that it is a common phenomena in these endohedrals." @default.
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- W2073312954 date "2000-10-01" @default.
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- W2073312954 title "Low-temperature bistability in the magnetic properties of solvent-including lanthanide metallofullerene crystals" @default.
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- W2073312954 doi "https://doi.org/10.1103/physrevb.62.8592" @default.
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