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- W2073313900 abstract "Trisubstituted alkenes have been prepared via intermolecular olefin cross-metathesis (CM) between α-olefins and symmetrically 1,1-disubstituted olefins using an imidazolylidene ruthenium benzylidene complex. Of particular interest is the synthesis of isoprenoid/prenyl groups by a simple solvent-free CM reaction with isobutylene. In addition, prenyl groups can also be installed by a cross-metathesis of 2-methyl-2-butene with a variety of α-olefins at room temperature with low catalyst loadings." @default.
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- W2073313900 date "2002-05-01" @default.
- W2073313900 modified "2023-10-17" @default.
- W2073313900 title "Synthesis of Symmetrical Trisubstituted Olefins by Cross Metathesis" @default.
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- W2073313900 doi "https://doi.org/10.1021/ol0259793" @default.
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