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• W2073340709 abstract "Zeolites going crackers: Brønsted acid sites in zeolites (H-FER, H-MFI, H-MOR) catalyze CH4-alkene reactions at high temperatures (>700 K) via carbonium-ion-like transition states. The ratio of rate constants for forward and reverse reactions (alkane alkylation-cracking, alkene dimerization-cracking) equal their respective equilibrium constants (KR). In contrast, relative rates of CH4 and alkene reactions with a given alkoxide are influenced by the local environment around acid sites." @default.
• W2073340709 created "2016-06-24" @default.
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• W2073340709 date "2011-05-05" @default.
• W2073340709 modified "2023-10-16" @default.
• W2073340709 title "Catalytic Alkylation Routes via Carbonium‐Ion‐Like Transition States on Acidic Zeolites" @default.
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• W2073340709 doi "https://doi.org/10.1002/cctc.201100051" @default.
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