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• W2073340802 startingPage "12180" @default.
• W2073340802 abstract "A new [2]rotaxane host system containing nitro-isophthalamide macrocycle and polyether functionalised pyridinium axle components is prepared via clipping and stoppering synthetic methodologies using chloride anion templation. After removing the chloride anion template, 1H NMR titration experiments reveal the unique interlocked host cavity to be highly selective for binding chloride and bromide in preference to basic oxoanions in competitive aqueous solvent mixtures. The rotaxane host system proved to be a superior anion complexant in comparison to the individual macrocycle and axle components. The anion binding affinity of the novel rotaxane is also investigated via molecular dynamics simulations and in general the structural data obtained corroborates the experimental solution anion recognition behaviour." @default.
• W2073340802 created "2016-06-24" @default.
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• W2073340802 date "2011-01-01" @default.
• W2073340802 modified "2023-10-17" @default.
• W2073340802 title "Clipping and stoppering anion templated synthesis of a [2]rotaxane host system" @default.
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• W2073340802 doi "https://doi.org/10.1039/c1dt10887e" @default.
• W2073340802 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21869981" @default.
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