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- W2073347359 abstract "Various bi- and trimetallic associations have been tested as catalysts for the selective oxidation of glyoxal into glyoxalic acid in aqueous phase. All catalysts were supported on carbon and consisted of a noble metal (Pd or Pt) in association with a second (or third) metal acting as promoter (Ru or Bi). Out of all the possible combinations, some families of catalysts were selected as interesting candidates and a detailed kinetic study was undertaken, in order to determine the rate constant associated with the formation of glyoxalic acid. In particular, the BiPt/C catalysts gave very high activity, but low selectivity (due to over-oxidation to oxalic acid), the PdRu/C catalysts gave the highest yields in glyoxalic acid, but with long reaction times and a marked sensitivity to the preparation procedure, while the trimetallic catalysts gave high yields in relatively short periods of time." @default.
- W2073347359 created "2016-06-24" @default.
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- W2073347359 date "2005-03-01" @default.
- W2073347359 modified "2023-10-14" @default.
- W2073347359 title "Bimetallic Bi–Pt, Ru–Pt and Ru–Pd and trimetallic catalysts for the selective oxidation of glyoxal into glyoxalic acid in aqueous phase" @default.
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- W2073347359 doi "https://doi.org/10.1016/j.apcata.2004.12.023" @default.
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