FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073356714> ?p ?o ?g. }

• W2073356714 endingPage "13493" @default.
• W2073356714 startingPage "13480" @default.
• W2073356714 abstract "Abstract Biooxidation of benzoic acid by Ralstonia eutropha B9 provides an unusual cyclohexadiene carboxy diol that contains a quaternary stereocentre. Tricarbonyliron derivatives of this chiron, on treatment with acid, give two isomeric η 5 ‐cyclohexadienyl complexes as observed by NMR spectroscopy. Both of these can be subjected to the addition of nucleophiles to provide isomeric cyclohexadiene complexes with new substituent patterns, several of which have been characterised crystallographically. De‐metallation of these provides a versatile library of cyclohexadiene building blocks, the utility of which is demonstrated by formal syntheses of oseltamivir. The mechanism of product formation and its stereochemical implications are discussed, as are the procedures undertaken to establish the enantiopurity of a representative cyclohexadiene product." @default.
• W2073356714 created "2016-06-24" @default.
• W2073356714 creator A5011464306 @default.
• W2073356714 creator A5056230871 @default.
• W2073356714 creator A5056709698 @default.
• W2073356714 creator A5081666022 @default.
• W2073356714 creator A5084137468 @default.
• W2073356714 date "2012-09-13" @default.
• W2073356714 modified "2023-10-18" @default.
• W2073356714 title "Valuable New Cyclohexadiene Building Blocks from Cationic η⁵-Iron-Carbonyl Complexes Derived from a Microbial Arene Oxidation Product" @default.
• W2073356714 cites W1029818560 @default.
• W2073356714 cites W1494726561 @default.
• W2073356714 cites W1523808595 @default.
• W2073356714 cites W1534150946 @default.
• W2073356714 cites W1546261541 @default.
• W2073356714 cites W1584639472 @default.
• W2073356714 cites W1590298204 @default.
• W2073356714 cites W1806222568 @default.
• W2073356714 cites W1827922301 @default.
• W2073356714 cites W194034590 @default.
• W2073356714 cites W1963677048 @default.
• W2073356714 cites W1963707693 @default.
• W2073356714 cites W1965161754 @default.
• W2073356714 cites W1967474416 @default.
• W2073356714 cites W1968149829 @default.
• W2073356714 cites W1968499917 @default.
• W2073356714 cites W1969262558 @default.
• W2073356714 cites W1969750557 @default.
• W2073356714 cites W1970100913 @default.
• W2073356714 cites W1971298459 @default.
• W2073356714 cites W1971967922 @default.
• W2073356714 cites W1973184372 @default.
• W2073356714 cites W1973881942 @default.
• W2073356714 cites W1975559501 @default.
• W2073356714 cites W1977839393 @default.
• W2073356714 cites W1978777166 @default.
• W2073356714 cites W1979311542 @default.
• W2073356714 cites W1979742098 @default.
• W2073356714 cites W1980210475 @default.
• W2073356714 cites W1982255161 @default.
• W2073356714 cites W1984166274 @default.
• W2073356714 cites W1984597377 @default.
• W2073356714 cites W1985275452 @default.
• W2073356714 cites W1986734551 @default.
• W2073356714 cites W1987777674 @default.
• W2073356714 cites W1988439828 @default.
• W2073356714 cites W1988637451 @default.
• W2073356714 cites W1989419584 @default.
• W2073356714 cites W1991990770 @default.
• W2073356714 cites W1992531225 @default.
• W2073356714 cites W1993585128 @default.
• W2073356714 cites W1994466819 @default.
• W2073356714 cites W1994881082 @default.
• W2073356714 cites W1994958134 @default.
• W2073356714 cites W1995215424 @default.
• W2073356714 cites W1995598226 @default.
• W2073356714 cites W1996317585 @default.
• W2073356714 cites W1996538208 @default.
• W2073356714 cites W1996635578 @default.
• W2073356714 cites W1996635705 @default.
• W2073356714 cites W1997562369 @default.
• W2073356714 cites W1997609050 @default.
• W2073356714 cites W1997721268 @default.
• W2073356714 cites W1998115351 @default.
• W2073356714 cites W1998767495 @default.
• W2073356714 cites W2000126093 @default.
• W2073356714 cites W2001500193 @default.
• W2073356714 cites W2002509504 @default.
• W2073356714 cites W2002607311 @default.
• W2073356714 cites W2005234239 @default.
• W2073356714 cites W2005619351 @default.
• W2073356714 cites W2005759407 @default.
• W2073356714 cites W2006243765 @default.
• W2073356714 cites W2006263816 @default.
• W2073356714 cites W2010371265 @default.
• W2073356714 cites W2010804325 @default.
• W2073356714 cites W2011034846 @default.
• W2073356714 cites W2012215388 @default.
• W2073356714 cites W2013414119 @default.
• W2073356714 cites W2014720691 @default.
• W2073356714 cites W2014861093 @default.
• W2073356714 cites W2015647419 @default.
• W2073356714 cites W2016261699 @default.
• W2073356714 cites W2016503235 @default.
• W2073356714 cites W2016978898 @default.
• W2073356714 cites W2021596192 @default.
• W2073356714 cites W2022090488 @default.
• W2073356714 cites W2022271628 @default.
• W2073356714 cites W2022665378 @default.
• W2073356714 cites W2023531064 @default.
• W2073356714 cites W2024654518 @default.
• W2073356714 cites W2024725467 @default.
• W2073356714 cites W2025465542 @default.
• W2073356714 cites W2026107937 @default.
• W2073356714 cites W2027548493 @default.
• W2073356714 cites W2029264119 @default.
• W2073356714 cites W2029548922 @default.
• W2073356714 cites W2031208756 @default.

• next