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- W2073366567 abstract "Die Oxymercurierungsprodukte des Homobarrelens (3) liefern bei der Demercurierung mit Metallhydriden, wie Natriumborhydrid, Lithiumaluminiumhydrid und Tributylzinnhydrid, z,T. umgelagerte Verbindungen mit Bicyclo[3.2.1]octa-2,6-dien-Gerust. Der Grad der Umlagerung hangt ab von der Art des Metallhydrids, der Temperatur und dem Losungsmittel. Ein Radikalmechanismus mit mehrmaliger Homoallylumlagerung wird vorgeschlagen. Bei den analogen Verbindungen des Bicyclo[2.2.2]octadiens findet keine derartige Umlagerung statt.Rearrangements on the Demercuration with Metal HydridesThe products of oxymercuration of homobarrelene (3) partly form rearranged products with the structure of bicyclo[3.2.1]octa-2,6-diene on the demercuration with metal hydrides such as sodium borohydride, lithium aluminium hydride, the temperature and the solvent. A radical mechanism with repeated homoallyl-rearrangement is proposed. A similar rearrangement, however, does not take place in the case of analogous compounds derived from bicyclo[2.2.2]octadienes." @default.
- W2073366567 created "2016-06-24" @default.
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- W2073366567 date "1976-12-01" @default.
- W2073366567 modified "2023-09-27" @default.
- W2073366567 title "Umlagerungsreaktionen bei der Demercurierung mit Metallhydriden" @default.
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- W2073366567 doi "https://doi.org/10.1002/cber.19761091207" @default.
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