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- W2073372364 abstract "Polymerization of ethylene over transition-metal exchanged montmorillonite (K 10) was studied at room temperature. It was found that over Ni2+ -Mont, dimerization of ethylene to n-butenes proceeded selectively. Over Cr3+-Mont, high polymerization occurred, and the polyethylene produced had a high melting point and density. The catalytic activities for the ethylene dimerization and polymerization were closely correlated with the acidity of the catalysts. The active sites for the ethylene dimerization consisted of nickel ion and Brønsted acid, while the active site for the polymerization was related to the Lewis acid, chromium ion." @default.
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- W2073372364 title "Ethylene polymerization over transition metal-exchanged montmorillonite catalysts" @default.
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- W2073372364 doi "https://doi.org/10.1016/0926-860x(93)80143-e" @default.
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