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- W2073373546 abstract "Vanadium(IV) is extracted synergically with thenoyltrifluoroacetone (HTTA) and trioctylphosphine oxide (TOPO) in cyclohexane as the mixed ligand complex, VO(TTA)2TOPO. The synergic extraction constant is 105.06. The system can be used for the substoichiometric extraction of vanadium(IV); vanadium(IV) is extracted at pH 4.0–5.0 with a substoichiometric amount of HTTA in the presence of an excess of TOPO. The substoichiometric process combined with isotope dilution was successfully applied to the determination of vanadium(IV) in NBS-1633 coal fly ash; the value found was 222.5 ± 3.5 μg g−1. The method is shown to be accurate and precise." @default.
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- W2073373546 date "1984-01-01" @default.
- W2073373546 modified "2023-09-27" @default.
- W2073373546 title "Substoichiometric liquid-liquid extraction and determination of vanadium based on the synergic effect of thenolytrifluoroacetone and trioctylphosphine oxide" @default.
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- W2073373546 doi "https://doi.org/10.1016/s0003-2670(00)84510-9" @default.
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