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- W2073387777 abstract "We have found that the reactions of PdCl2 and/or PtCl2 with ylids of the type PhnZCHC(O)CH3 (n=3, ZP, As; n=2, ZS) in refluxing CH3CN produce dinuclear C-bound, ortho-metalated complexes analogous to the [Pt(μ-Cl)(CH3COCHP(C6H4)(C6H5)2]2 complex previously reported by our laboratory. In addition, we have succeeded in forming a ‘back-door’ C-bound, ortho-metalated dinuclear complex by refluxing PdCl2 and the ylid (n-C4H9)3PCHC(O)Ph in CH3CN: [Pd(μ-Cl)(C6H4COCHP(n-C4H9)3]2. This and the preceding complexes' syntheses and structures are discussed in terms of their 1H, 13C, and 31P NMR spectra, as well as those produced by additional reactions of PtCl2 and PdCl2 in CH3CN with ylids of the type PhCOCHZPh3 (ZP, As), i.e., ylids having both a ‘front-doof’ and a ‘back-door’ available for ortho-metalation." @default.
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- W2073387777 date "1986-08-01" @default.
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- W2073387777 title "Synthesis of ortho-metalated palladium(II) and platinum(II) complexes of phosphonium, arsonium and sulfonium ylids" @default.
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- W2073387777 doi "https://doi.org/10.1016/s0020-1693(00)86408-7" @default.
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