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- W2073409489 abstract "Hydration of acetylene under steady-state conditions around 450 K proceeds on Cd-clinoptilolite without catalyst deactivation and formation of by-products. Reaction rates were determined under steady-state conditions at different partial pressures of acetylene, water, and acetaldehyde. In relation with the results, rate equations for different kinetic models were evaluated. Langmuir-Hinshelwood kinetics was established. According to this model, acetylene and water must adsorb on similar sites, and the surface reaction between the adsorbed reactants is the rate-determining step, which is followed by equilibrated desorption of the produced acetaldehyde." @default.
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- W2073409489 date "2001-05-16" @default.
- W2073409489 modified "2023-09-27" @default.
- W2073409489 title "Acetylene-Hydration Kinetics on Cadmium-Exchanged Clinoptilolite Catalyst, Preliminary Communication" @default.
- W2073409489 doi "https://doi.org/10.1002/1522-2675(20010516)84:5<1157::aid-hlca1157>3.0.co;2-7" @default.
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