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- W2073409573 abstract "Batch experiments were performed to examine the BrO 3 - uptake from dilute aqueous solutions on amorphous aluminum hydroxide (Cl - type), which was synthesized by addition of a 3 mol/dm 3 NaOH solution to a 0.1 mol/dm 3 AlCl 3 solution until the pH reached 5.8. The uptake from a 0.78 μmol/dm 3 BrO 3 solution (100 μg of BrO 3 /dm 3 ) was rapid: equilibrium was attained within 3 min. The BrO - 3 uptake was found to decrease slowly at pH 4-8 and rapidly at pH >8. The isotherm for BrO - 3 uptake was well fitted with the Freundlich isotherm model. From distribution coefficient (K d ) values determined from mixed solutions containing 0.10, 1.0, and 2.0 mmol/dm' NaCl, NaBrO 3 , NaNO 3 , Na 2 SO 4 , and Na 2 CO 3 the selectivity order was reported as NO 3 < BrO 3 < SO 2- 4 at a pH range 4.8-7.9. These results suggest that the BrO 3 uptake on the amorphous aluminum hydroxide occurs through an outer-sphere complex reaction." @default.
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- W2073409573 date "2010-08-17" @default.
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- W2073409573 title "Uptake of Bromate Ion on Amorphous Aluminum Hydroxide" @default.
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- W2073409573 doi "https://doi.org/10.1021/ie901705n" @default.
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