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- W2073430600 abstract "A new three-phase separation phenomenon was observed, in which two water-immiscible liquid phases (a first and a second phase) were immediately formed from a homogeneous aqueous solution. This phenomenon appeared on the charge neutralization (e.g., pKa value of HPFOA was 1.01, at I = 0.1, 20°C) of the perfluorooctanoate ion (PFOA-) with a proton (H+) in aqueous solution containing a small amount of a water-miscible organic solvent such as dimethyl sulfoxide (DMSO) and PFOA- ion. The optimum conditions for the three-phase separation behavior were defined as follows: the pH was 0.42 to 0.46, the total concentration of PFOA- ion was 0.025 to 0.032 mol dm-3, and that of DMSO was 0.90 to 2.43 mol dm-3." @default.
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- W2073430600 date "1995-07-01" @default.
- W2073430600 modified "2023-10-18" @default.
- W2073430600 title "A pH-Dependent Three-Phase Separation Phenomenon with a Perfluorooctanoic Acid/Dimethylsulfoxide/Water System" @default.
- W2073430600 doi "https://doi.org/10.1006/jcis.1995.1322" @default.
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