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- W2073447632 abstract "Electrical conductivity and relaxation data were measured for glasses of composition 0.242[ X K 2 O+(1‐ X )Na 2 O]‐0.758SiO 2 from 25° to 205°C and in the dilute Na + ion composition range X = 0.9 to 1. The decrease in electrical conductivity σ when the majority alkali K + is replaced with the foreign alkali Na + is most rapid in the very dilute range X = 0.98 to 1 and becomes less rapid at larger Na + contents. The electric field relaxation times agree well with the single‐alkali mechanical relaxation times. The electric field relaxation function becomes more exponential with increasing foreign alkali content, indicating a corresponding decrease in the concentration of mobile ions. Attempts to account for the decrease in σ with increasing foreign alkali content by assuming that the single‐alkali glass is a strong electrolyte and that the foreign alkali complexes with and immobilizes the majority alkali were unsuccessful. Calculated values of the number of majority alkali ions complexed by a foreign‐alkali ion were unreasonably large." @default.
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- W2073447632 date "1980-07-01" @default.
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- W2073447632 title "Mixed‐Alkali Effect in the Dilute Foreign‐Alkali Region. Failure of the Strong Electrolyte/Cationic Interaction Model" @default.
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- W2073447632 doi "https://doi.org/10.1111/j.1151-2916.1980.tb10212.x" @default.
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