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- W2073449788 abstract "Ninety chiral centers and a molecular mass of 11354 Da are the outstanding features of the largest C3-symmetric, chiral dendrimer to date. As general approach to these chiral polyether compounds (1) styrenes or stilbenes are converted into 1,2-diols by asymmetric dihydroxylation; (2) the resulting building blocks are then linked together to form dendrons by a uniquely effective ether-forming reaction, in which the vincinal hydroxyls are alkylated with benzylic bromides by using KOH pellets in refluxing toluene; (3) the dendrons are coupled to a core unit such as 1,3,5-benzene-tricarbonyl trichloride." @default.
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- W2073449788 date "1996-02-02" @default.
- W2073449788 modified "2023-10-16" @default.
- W2073449788 title "Asymmetric Dihydroxylation Enables Rapid Construction of Chiral Dendrimers Based on 1,2-Diols" @default.
- W2073449788 doi "https://doi.org/10.1002/anie.199601821" @default.
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