Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073451102> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2073451102 abstract "1. Rhodanese inactivation by 2,4,6-trinitrobenzenesulphonate, in the presence of n-butylamine in the reaction medium, has been studied by a kinetic analysis of the data, based on the assumption that enzyme inactivation is brought about by direct reaction of this with the modifying agent. 2. Initial reaction rates for rhodanese activity loss were determined by a mathematical analysis of the first three recorded values of rhodanese residual activity. 3. It was found that fractional rhodanese activity values, at infinite reaction time with 2,4,6-trinitrobenzenesulphonate (end-point values), were significantly lower than the values calculated on the assumption of rhodanese inactivation being entirely due to direct trinitrophenylation of enzyme protein. 4. Also, initial enzyme inactivation values were higher in the presence, rather than in the absence, of n-butylamine. 5. These results indicate that 2,4,6-trinitrobenzenesulphonate-induced rhodanese inactivation, in the presence of n-butylamine in the reaction medium, is due to the generation of a highly reactive, unstable intermediate, probably a free radical species." @default.
- W2073451102 created "2016-06-24" @default.
- W2073451102 creator A5043913271 @default.
- W2073451102 creator A5045344506 @default.
- W2073451102 date "1992-01-01" @default.
- W2073451102 modified "2023-09-27" @default.
- W2073451102 title "Kinetic evidence for the existence of an unstable intermediate in the trinitrophenylation-induced rhodanese inactivation reaction" @default.
- W2073451102 cites W1482128126 @default.
- W2073451102 cites W1532383707 @default.
- W2073451102 cites W19547930 @default.
- W2073451102 cites W1957655620 @default.
- W2073451102 cites W2032782582 @default.
- W2073451102 cites W2049102755 @default.
- W2073451102 cites W2069925061 @default.
- W2073451102 cites W2075801535 @default.
- W2073451102 cites W2154637522 @default.
- W2073451102 cites W2212219374 @default.
- W2073451102 cites W2216809518 @default.
- W2073451102 cites W2344254904 @default.
- W2073451102 cites W2413946442 @default.
- W2073451102 cites W2434871739 @default.
- W2073451102 doi "https://doi.org/10.1016/0020-711x(92)90373-9" @default.
- W2073451102 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/1397498" @default.
- W2073451102 hasPublicationYear "1992" @default.
- W2073451102 type Work @default.
- W2073451102 sameAs 2073451102 @default.
- W2073451102 citedByCount "0" @default.
- W2073451102 crossrefType "journal-article" @default.
- W2073451102 hasAuthorship W2073451102A5043913271 @default.
- W2073451102 hasAuthorship W2073451102A5045344506 @default.
- W2073451102 hasConcept C161790260 @default.
- W2073451102 hasConcept C175113610 @default.
- W2073451102 hasConcept C181199279 @default.
- W2073451102 hasConcept C185592680 @default.
- W2073451102 hasConcept C2779033446 @default.
- W2073451102 hasConcept C2779201268 @default.
- W2073451102 hasConcept C2780637352 @default.
- W2073451102 hasConcept C55493867 @default.
- W2073451102 hasConcept C71240020 @default.
- W2073451102 hasConceptScore W2073451102C161790260 @default.
- W2073451102 hasConceptScore W2073451102C175113610 @default.
- W2073451102 hasConceptScore W2073451102C181199279 @default.
- W2073451102 hasConceptScore W2073451102C185592680 @default.
- W2073451102 hasConceptScore W2073451102C2779033446 @default.
- W2073451102 hasConceptScore W2073451102C2779201268 @default.
- W2073451102 hasConceptScore W2073451102C2780637352 @default.
- W2073451102 hasConceptScore W2073451102C55493867 @default.
- W2073451102 hasConceptScore W2073451102C71240020 @default.
- W2073451102 hasLocation W20734511021 @default.
- W2073451102 hasLocation W20734511022 @default.
- W2073451102 hasOpenAccess W2073451102 @default.
- W2073451102 hasPrimaryLocation W20734511021 @default.
- W2073451102 hasRelatedWork W1480777598 @default.
- W2073451102 hasRelatedWork W1530076784 @default.
- W2073451102 hasRelatedWork W1860791487 @default.
- W2073451102 hasRelatedWork W1973200129 @default.
- W2073451102 hasRelatedWork W1976255212 @default.
- W2073451102 hasRelatedWork W2009419813 @default.
- W2073451102 hasRelatedWork W2012693179 @default.
- W2073451102 hasRelatedWork W2030487804 @default.
- W2073451102 hasRelatedWork W2099847370 @default.
- W2073451102 hasRelatedWork W4225774004 @default.
- W2073451102 isParatext "false" @default.
- W2073451102 isRetracted "false" @default.
- W2073451102 magId "2073451102" @default.
- W2073451102 workType "article" @default.