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• W2073451846 abstract "We have carried out hard X-ray photoemission spectroscopy on YbCdCu4 and YbSnCu4 at hν ∼ 6 keV in order to investigate electronic structure, and compared the results with that of the valence transition compound YbInCu4. Based on fitting analyses of the Yb 3d spectra, the Yb valences of YbCdCu4 and YbSnCu4 are estimated to be 2.96 ± 0.01 and 2.86 ± 0.01 at 300 K, respectively, and the valences slightly decrease becoming closer to divalent on cooling. The Cu 2p3/2 level does not follow the chemical trend on going from YbCdCu4, to YbInCu4, and to YbSnCu4. The lowest binding energy of the Cu 2p3/2 level for YbInCu4 suggests that the large number of conduction electrons distributes over the Cu site in YbInCu4 and the excess conduction electrons play an important role for the valence transition of YbInCu4." @default.
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• W2073451846 date "2011-04-01" @default.
• W2073451846 modified "2023-10-17" @default.
• W2073451846 title "X-dependent electronic structure of YbXCu4 (X=Cd, In, Sn) investigated by hard X-ray photoemission spectroscopy" @default.
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• W2073451846 doi "https://doi.org/10.1016/j.elspec.2010.10.007" @default.
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