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- W2073467440 abstract "The behaviour of the system of intermolecular hydrogen bonds during the deformation of solid polymers has been studied theoretically. The relation of changes of bond concentration to extent of deformation and intensity of molecular mobility has been determined, taking into account the rupture and partial reverse restoration of the bonds. The probability of restoration of broken bonds was calculated as a function of polar group concentration in the polymer. The calculations were compared with available experimental values and this showed there was agreement between theory and experiment. The dependence of the volume deformed at the microlevel on the extent of macrodeformation was estimated; the scale of displacement of kinetic units in the region of β-transformation of styrene copolymers was determined. The relation of this relaxation process with the motion of parts of the main chains was confirmed. The analysis of the scale of displacement showed that the latter motion occurs by means of the rotation of parts around the chain, through angles of π/2 to π." @default.
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- W2073467440 date "1982-01-01" @default.
- W2073467440 modified "2023-09-27" @default.
- W2073467440 title "Dynamics of the system of intermolecular hydrogen bonds in strained polymers" @default.
- W2073467440 cites W1999415198 @default.
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- W2073467440 doi "https://doi.org/10.1016/0032-3950(82)90271-4" @default.
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