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- W2073468094 abstract "Iodophenyl-terminated organic monolayers were prepared by thermally induced hydrosilylation on hydrogen-terminated silicon (1 1 1) surfaces. The films were characterized by ellipsometry, contact-angle goniometry, and X-ray photoelectron spectroscopy (XPS). To modify the surface chemistry and the structure of the monolayers, the Sonogashira coupling reaction was performed on the as-prepared monolayers. The iodophenyl groups on the film surfaces reacted with 1-ethynyl-4-fluorobenzene or the 1-chloro-4-ethynylbenzene under the standard Sonogashira reaction conditions for attaching conjugated molecules via the formation of CC bonds. It is expected that this surface coupling reaction will present a new method to modify the surface chemistry and the structure of monolayers." @default.
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- W2073468094 date "2008-12-01" @default.
- W2073468094 modified "2023-10-12" @default.
- W2073468094 title "Pd-catalyzed coupling reaction on the organic monolayer: Sonogashira reaction on the silicon (111) surfaces" @default.
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- W2073468094 doi "https://doi.org/10.1016/j.apsusc.2008.07.175" @default.
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