FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073472008> ?p ?o ?g. }

• W2073472008 endingPage "288" @default.
• W2073472008 startingPage "277" @default.
• W2073472008 abstract "Microheterogeneous catalytic systems using aqueous suspensions of rhodium particles are proved to be efficient for alkene hydrogenation in biphasic liquid-liquid medium provided that the method of stabilization and the interfacial phenomena are properly chosen and controlled. Aqueous supensions stabilized by specially designed trianionic molecules or by hydrophilic polymer (PVA) have been studied. A series of trisulfonated molecules 1 with modulated solution behaviors (surfactant or hydrotrope) depending on the nature of the substituents has been used to stabilize aqueous suspensions of oxidized (polar) or reduced (non polar) rhodium particles. Stabilization of polar particles occurs whatever the substituents when stabilization of metallic apolar particles requires surfactants bearing a significant lipophilic part. In the former case, highly stable suspensions of rhodium nanoparticles with controlled size are obtained in micellar solutions. Both oxidized and reduced rhodium suspensions efficiently catalyzed octene hydrogenation in liquid-liquid medium and it is established that high activity and possible recovery and recycling of the catalyst can be achieved by the control of interfacial parameter e.g. the interfacial tension. In the same way, common polymer-protected colloidal suspensions of Rh(0) particles are proved to efficiently catalyze hydrogenation in two liquid phases systems provided that optimized amounts of surfactants are added to reduce the interfacial tension without emulsification. From these results a relationship between interfacial tension and catalytic activity in biphasic system is proposed." @default.
• W2073472008 created "2016-06-24" @default.
• W2073472008 creator A5001302945 @default.
• W2073472008 creator A5053998254 @default.
• W2073472008 creator A5067816250 @default.
• W2073472008 creator A5077307091 @default.
• W2073472008 date "1997-02-01" @default.
• W2073472008 modified "2023-09-30" @default.
• W2073472008 title "Biphasic liquid-liquid hydrogenation catalysis by aqueous colloidal suspensions of rhodium: The choice of the protective-colloid agent and the role of interfacial phenomena" @default.
• W2073472008 cites W1964094366 @default.
• W2073472008 cites W1966044081 @default.
• W2073472008 cites W1970755033 @default.
• W2073472008 cites W1970949987 @default.
• W2073472008 cites W1977739771 @default.
• W2073472008 cites W1986476492 @default.
• W2073472008 cites W1998774808 @default.
• W2073472008 cites W2000290041 @default.
• W2073472008 cites W2000826223 @default.
• W2073472008 cites W2002679234 @default.
• W2073472008 cites W2005716167 @default.
• W2073472008 cites W2007238709 @default.
• W2073472008 cites W2009981131 @default.
• W2073472008 cites W2010739305 @default.
• W2073472008 cites W2024980718 @default.
• W2073472008 cites W2029358073 @default.
• W2073472008 cites W2034124623 @default.
• W2073472008 cites W2036356999 @default.
• W2073472008 cites W2050183781 @default.
• W2073472008 cites W2055112283 @default.
• W2073472008 cites W2062492817 @default.
• W2073472008 cites W2065095134 @default.
• W2073472008 cites W2066864014 @default.
• W2073472008 cites W2068443239 @default.
• W2073472008 cites W2073552100 @default.
• W2073472008 cites W2073847330 @default.
• W2073472008 cites W2077076648 @default.
• W2073472008 cites W2083238268 @default.
• W2073472008 cites W2086637901 @default.
• W2073472008 cites W2087854009 @default.
• W2073472008 cites W2087947900 @default.
• W2073472008 cites W2092503691 @default.
• W2073472008 cites W211584946 @default.
• W2073472008 cites W2134550442 @default.
• W2073472008 cites W2157155831 @default.
• W2073472008 doi "https://doi.org/10.1016/s1381-1169(96)00189-6" @default.
• W2073472008 hasPublicationYear "1997" @default.
• W2073472008 type Work @default.
• W2073472008 sameAs 2073472008 @default.
• W2073472008 citedByCount "48" @default.
• W2073472008 countsByYear W20734720082012 @default.
• W2073472008 countsByYear W20734720082013 @default.
• W2073472008 countsByYear W20734720082014 @default.
• W2073472008 countsByYear W20734720082015 @default.
• W2073472008 countsByYear W20734720082016 @default.
• W2073472008 countsByYear W20734720082017 @default.
• W2073472008 countsByYear W20734720082020 @default.
• W2073472008 countsByYear W20734720082021 @default.
• W2073472008 crossrefType "journal-article" @default.
• W2073472008 hasAuthorship W2073472008A5001302945 @default.
• W2073472008 hasAuthorship W2073472008A5053998254 @default.
• W2073472008 hasAuthorship W2073472008A5067816250 @default.
• W2073472008 hasAuthorship W2073472008A5077307091 @default.
• W2073472008 hasConcept C111368507 @default.
• W2073472008 hasConcept C121332964 @default.
• W2073472008 hasConcept C127313418 @default.
• W2073472008 hasConcept C127413603 @default.
• W2073472008 hasConcept C155672457 @default.
• W2073472008 hasConcept C161790260 @default.
• W2073472008 hasConcept C178790620 @default.
• W2073472008 hasConcept C184651966 @default.
• W2073472008 hasConcept C185592680 @default.
• W2073472008 hasConcept C188027245 @default.
• W2073472008 hasConcept C192562407 @default.
• W2073472008 hasConcept C2776254738 @default.
• W2073472008 hasConcept C2778517922 @default.
• W2073472008 hasConcept C32909587 @default.
• W2073472008 hasConcept C42360764 @default.
• W2073472008 hasConcept C521398313 @default.
• W2073472008 hasConcept C521977710 @default.
• W2073472008 hasConcept C58226133 @default.
• W2073472008 hasConcept C59789625 @default.
• W2073472008 hasConcept C62520636 @default.
• W2073472008 hasConcept C8892853 @default.
• W2073472008 hasConceptScore W2073472008C111368507 @default.
• W2073472008 hasConceptScore W2073472008C121332964 @default.
• W2073472008 hasConceptScore W2073472008C127313418 @default.
• W2073472008 hasConceptScore W2073472008C127413603 @default.
• W2073472008 hasConceptScore W2073472008C155672457 @default.
• W2073472008 hasConceptScore W2073472008C161790260 @default.
• W2073472008 hasConceptScore W2073472008C178790620 @default.
• W2073472008 hasConceptScore W2073472008C184651966 @default.
• W2073472008 hasConceptScore W2073472008C185592680 @default.
• W2073472008 hasConceptScore W2073472008C188027245 @default.
• W2073472008 hasConceptScore W2073472008C192562407 @default.
• W2073472008 hasConceptScore W2073472008C2776254738 @default.
• W2073472008 hasConceptScore W2073472008C2778517922 @default.
• W2073472008 hasConceptScore W2073472008C32909587 @default.
• W2073472008 hasConceptScore W2073472008C42360764 @default.

• next