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- W2073480587 abstract "The adsorption of NO on a clean Pt(100) surface was studied by Auger spectroscopy (AES), LEED and ultraviolet and X-ray photoemission spectroscopies (UPS and XPS) at temperatures of 40–400°C. In accord with previous work only molecular NO was found to adsorb in the low temperature region 40–100°C. This molecular NO layer dissociated into nitrogen and oxygen during heating of the crystal at 180–220°C. The presence of atomic oxygen after dissociation was verified by AES, UPS and XPS. The UPS data showed a typical oxygen emission peak near 5.6 eV below E f while XPS indicated a shift of 1.5 eV in the oxygen 1s line towards lower binding energy. The NO dissociation was accompanied by an increase in work function of about 0.4 eV. The electron binding energy shifts of O(1s) and N(1s) for adsorbed NO were 6.8 and 4.2 eV, respectively; their inequality is interpreted as suggestive of a non-linearly bonded NO molecule. During heating the dissociation of NO competes with NO desorption. This behaviour has interesting implications in connection with the potential energy diagram of adsorbed NO." @default.
- W2073480587 created "2016-06-24" @default.
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- W2073480587 date "1977-01-01" @default.
- W2073480587 modified "2023-10-16" @default.
- W2073480587 title "Photoelectron spectroscopy of NO adsorbed on Pt(100)" @default.
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- W2073480587 doi "https://doi.org/10.1016/0039-6028(77)90427-7" @default.
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