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- W2073485106 abstract "In this work, diazonium-based photoinitiators were electrografted on gold electrodes to provide specific, selective and ultrasensitive molecularly imprinted polymer (MIP) grafts for the detection of melamine. This toxic molecule was used as a template, while methacrylic acid (MAA) and ethylene glycol dimethacrylate (EGDMA) were the functional and crosslinking monomers, respectively. Surface-initiated photopolymerization was conducted because it is a simple and versatile mean for making ultrathin MIP grafts (∼25 nm thick). Both cyclic and square wave voltammetry (SWV) were used for investigating rebinding melamine by the MIP grafts. However, the latter permitted to achieve ultrasensitive detection down to 7.7 × 10−10 mol/L in PBS and 3.1 × 10−10 mol/L in milk. Recovery was found to be very good, levelling off at 92%." @default.
- W2073485106 created "2016-06-24" @default.
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- W2073485106 date "2013-06-01" @default.
- W2073485106 modified "2023-10-03" @default.
- W2073485106 title "Melamine-imprinted polymer grafts through surface photopolymerization initiated by aryl layers from diazonium salts" @default.
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- W2073485106 doi "https://doi.org/10.1016/j.foodcont.2012.10.013" @default.
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