FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073492997> ?p ?o ?g. }

• W2073492997 endingPage "39" @default.
• W2073492997 startingPage "33" @default.
• W2073492997 abstract "An effective design of solid acid catalysts for synthesis of bisphenol-A was investigated using organic–inorganic dual modification of heteropolyacids. Among various solid acids, partially Cs-ion exchanged tungstophosphate (Cs2.5H0.5PW12O40) showed the highest turnover frequency, i.e., the initial reaction rate per acid site. The acid strengths estimated by differential heat of ammonia adsorption showed that relatively moderate acid strength is optimum for the intrinsic activity of acid sites. Cs2.5H0.5PW12O40 was further modified by immobilization of mercapto compounds. The addition of 2-diethylamino-ethanethiol (DEAT) to Cs2.5H0.5PW12O40 significantly enhanced both activity and selectivity. When the ratio of DEAT and protonic acid site was unity, the designed catalyst showed comparable bisphenol-A yield and higher turnover number and frequency than those of a conventional ion-exchange resin. The high catalytic activity of the dual modified heteropolyacid is attributed to the microscopically designed active center composed of inorganic protonic acid coupled with immobilized organic thiol group." @default.
• W2073492997 created "2016-06-24" @default.
• W2073492997 creator A5020206340 @default.
• W2073492997 creator A5020214710 @default.
• W2073492997 creator A5066167107 @default.
• W2073492997 creator A5073111678 @default.
• W2073492997 creator A5081972561 @default.
• W2073492997 creator A5088917747 @default.
• W2073492997 date "2010-05-31" @default.
• W2073492997 modified "2023-10-16" @default.
• W2073492997 title "Design of active centers for bisphenol-A synthesis by organic–inorganic dual modification of heteropolyacid" @default.
• W2073492997 cites W1966329819 @default.
• W2073492997 cites W1972400806 @default.
• W2073492997 cites W1987612589 @default.
• W2073492997 cites W1992290847 @default.
• W2073492997 cites W2013006445 @default.
• W2073492997 cites W2031005081 @default.
• W2073492997 cites W2032571474 @default.
• W2073492997 cites W2059516132 @default.
• W2073492997 cites W2063128505 @default.
• W2073492997 cites W2065477766 @default.
• W2073492997 cites W2074955442 @default.
• W2073492997 cites W2093954615 @default.
• W2073492997 cites W2094336203 @default.
• W2073492997 cites W2157584231 @default.
• W2073492997 cites W568941435 @default.
• W2073492997 doi "https://doi.org/10.1016/j.apcata.2010.03.025" @default.
• W2073492997 hasPublicationYear "2010" @default.
• W2073492997 type Work @default.
• W2073492997 sameAs 2073492997 @default.
• W2073492997 citedByCount "26" @default.
• W2073492997 countsByYear W20734929972012 @default.
• W2073492997 countsByYear W20734929972013 @default.
• W2073492997 countsByYear W20734929972014 @default.
• W2073492997 countsByYear W20734929972015 @default.
• W2073492997 countsByYear W20734929972016 @default.
• W2073492997 countsByYear W20734929972017 @default.
• W2073492997 countsByYear W20734929972019 @default.
• W2073492997 countsByYear W20734929972020 @default.
• W2073492997 countsByYear W20734929972022 @default.
• W2073492997 countsByYear W20734929972023 @default.
• W2073492997 crossrefType "journal-article" @default.
• W2073492997 hasAuthorship W2073492997A5020206340 @default.
• W2073492997 hasAuthorship W2073492997A5020214710 @default.
• W2073492997 hasAuthorship W2073492997A5066167107 @default.
• W2073492997 hasAuthorship W2073492997A5073111678 @default.
• W2073492997 hasAuthorship W2073492997A5081972561 @default.
• W2073492997 hasAuthorship W2073492997A5088917747 @default.
• W2073492997 hasConcept C117760992 @default.
• W2073492997 hasConcept C118792377 @default.
• W2073492997 hasConcept C134121241 @default.
• W2073492997 hasConcept C13965031 @default.
• W2073492997 hasConcept C145148216 @default.
• W2073492997 hasConcept C150394285 @default.
• W2073492997 hasConcept C161790260 @default.
• W2073492997 hasConcept C166595027 @default.
• W2073492997 hasConcept C178790620 @default.
• W2073492997 hasConcept C179104552 @default.
• W2073492997 hasConcept C185592680 @default.
• W2073492997 hasConcept C191897082 @default.
• W2073492997 hasConcept C192562407 @default.
• W2073492997 hasConcept C2778077586 @default.
• W2073492997 hasConcept C2778861492 @default.
• W2073492997 hasConcept C2779684741 @default.
• W2073492997 hasConcept C2779848963 @default.
• W2073492997 hasConcept C2781047139 @default.
• W2073492997 hasConcept C2781324293 @default.
• W2073492997 hasConcept C73969872 @default.
• W2073492997 hasConceptScore W2073492997C117760992 @default.
• W2073492997 hasConceptScore W2073492997C118792377 @default.
• W2073492997 hasConceptScore W2073492997C134121241 @default.
• W2073492997 hasConceptScore W2073492997C13965031 @default.
• W2073492997 hasConceptScore W2073492997C145148216 @default.
• W2073492997 hasConceptScore W2073492997C150394285 @default.
• W2073492997 hasConceptScore W2073492997C161790260 @default.
• W2073492997 hasConceptScore W2073492997C166595027 @default.
• W2073492997 hasConceptScore W2073492997C178790620 @default.
• W2073492997 hasConceptScore W2073492997C179104552 @default.
• W2073492997 hasConceptScore W2073492997C185592680 @default.
• W2073492997 hasConceptScore W2073492997C191897082 @default.
• W2073492997 hasConceptScore W2073492997C192562407 @default.
• W2073492997 hasConceptScore W2073492997C2778077586 @default.
• W2073492997 hasConceptScore W2073492997C2778861492 @default.
• W2073492997 hasConceptScore W2073492997C2779684741 @default.
• W2073492997 hasConceptScore W2073492997C2779848963 @default.
• W2073492997 hasConceptScore W2073492997C2781047139 @default.
• W2073492997 hasConceptScore W2073492997C2781324293 @default.
• W2073492997 hasConceptScore W2073492997C73969872 @default.
• W2073492997 hasIssue "1-2" @default.
• W2073492997 hasLocation W20734929971 @default.
• W2073492997 hasOpenAccess W2073492997 @default.
• W2073492997 hasPrimaryLocation W20734929971 @default.
• W2073492997 hasRelatedWork W2012412731 @default.
• W2073492997 hasRelatedWork W2361382342 @default.
• W2073492997 hasRelatedWork W2370877264 @default.
• W2073492997 hasRelatedWork W2374102295 @default.
• W2073492997 hasRelatedWork W2379757510 @default.
• W2073492997 hasRelatedWork W2383060123 @default.

• next