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- W2073501899 abstract "Five ionic assemblies of octacoordinated cyano complexes of molybdenum and tungsten with protonated cyclam (1,4,8,11-tetraazacyclotetradecane) and tmc (1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) have been obtained: (cyclamH4)[MoIV(CN)8]·1.5H2O (1), (cyclamH2)(cyclamH4)[WV(CN)8]2·4H2O (2), (cyclamH4)[WV(CN)8]Cl·4H2O (3), (tmcH4)(tmcH2)[WV(CN)8]2·4H2O (4) and (cyclamH4)[WIV(CN)6(bpy)]2·12H2O (5) (bpy = 2,2′-bipyridine). The presence of 3d metal cations as a template led to partly protonated cyclams in 2 and 4, where for the first time cyclam and tmc cations of different degree of protonation are encountered within one structure. Compounds 2, 3 and 5 crystallise in triclinic system space group P1¯, while 4 crystallises in monoclinic system space group P21/c. Compound 1 shows the highest symmetry of the lattice: orthorombic system space group I41/a. Thermogravimetric analyses of 1, 3 and 4 show the presence of stable anhydrous phase below 140 °C." @default.
- W2073501899 created "2016-06-24" @default.
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- W2073501899 date "2012-10-01" @default.
- W2073501899 modified "2023-09-23" @default.
- W2073501899 title "Cyclams with varied degree of protonation in the assemblies with cyano complexes of Mo and W" @default.
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- W2073501899 doi "https://doi.org/10.1016/j.poly.2012.08.020" @default.
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