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• W2073515512 abstract "Abstract Batch adsorption studies were carried out for the assessment of the adsorptive interactions of the system composed of humic acid, Cr(VI) and TiO 2 . These were preceded by a thorough investigation of the effect of the chromium ion concentration on the adsorption of humic acid onto TiO 2 . The adsorption equilibrium of total chromium, humic acid, and titanium dioxide in water were examined separately and in all combinations in order to distinguish the effects based on the interaction of the components. The adsorption data for the binary system as well as the ternary system were modeled with a simple Freundlich model and the model parameters were compared in terms of Cr(VI) and humic acid as expressed by Color 436 (color forming moieties) and UV 254 (UV absorbing centers) parameters. In binary systems composed of Cr(VI) and TiO 2 no direct relationship could be assessed between adsorption capacity values ( K F ) and changes in chromium ion concentration. Chromium ion and humic acid interactions were followed by UV-Vis spectra. A minor change irrespective of added chromium ion concentration was observed for Color 436 and UV 254 parameters of humic acid ( 2 , increasing Cr(VI) concentration five-fold did not cause drastic changes in the adsorption capacity values in terms of Cr(VI) concentration. On the other hand, the adsorption capacity values for color forming moieties as well as for UV absorbing centers of humic acid exhibited a decreasing trend with respect to increasing chromium ion concentration." @default.
• W2073515512 created "2016-06-24" @default.
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• W2073515512 date "2004-06-10" @default.
• W2073515512 modified "2023-09-25" @default.
• W2073515512 title "Evaluation of humic acid, chromium (VI) and TiO2 ternary system in relation to adsorptive interactions" @default.
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• W2073515512 doi "https://doi.org/10.1016/j.apcatb.2003.12.015" @default.
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