FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073527547> ?p ?o ?g. }

• W2073527547 endingPage "4398" @default.
• W2073527547 startingPage "4398" @default.
• W2073527547 abstract "A series of Pt(II) bipyridyl complexes with different aryl substituents (Ar = naphthyl (1a), anthryl (1b), pyrenyl (1c) and phenothiazyl (1d)) on the fluorenylacetylide ligands are synthesized and investigated. The influence of the aryl substituent on the photophysics of these complexes is systematically investigated by spectroscopic methods and simulated by time dependent density functional theory (TD-DFT). All complexes exhibit ligand-centered (1)π,π* transitions significantly admixed with the metal-to-ligand charge transfer ((1)MLCT)/ligand-to-ligand charge transfer ((1)LLCT) transitions in the UV and blue spectral region, and broad, structureless (1)MLCT/(1)LLCT absorption bands in the visible spectral region. All complexes are emissive in solution at room temperature, with the fluorescence originating predominantly from the (1)MLCT/(1)LLCT states. The triplet emitting state is dominated by the (3)π,π* state localized on the fluorenylacetylide motif and mixed with some (3)ML'CT character (metal-to-fluorenylacetylide ligand charge transfer) for 1a, 1b and 1d. For 1c, the phosphorescence predominantly originates from the pyrene localized (3)π,π* state. The variation in the photophysical properties is related to the twisting angle of the aryl substituent from the fluorenyl plane, which defines the conjugation between the substituents and fluorenylacetylide ligands and, consequently, alters the energy and intensity of absorption and emission in these complexes. also exhibit broadband triplet excited-state absorption in the visible spectral region. Therefore, they show strong reverse saturable absorption at 532 nm for nanosecond laser pulses as demonstrated by the nonlinear transmission experiment." @default.
• W2073527547 created "2016-06-24" @default.
• W2073527547 creator A5019365638 @default.
• W2073527547 creator A5043270824 @default.
• W2073527547 creator A5057105243 @default.
• W2073527547 creator A5071822893 @default.
• W2073527547 creator A5087381063 @default.
• W2073527547 date "2013-01-01" @default.
• W2073527547 modified "2023-10-14" @default.
• W2073527547 title "Synthesis, photophysics and reverse saturable absorption of bipyridyl platinum(ii) bis(arylfluorenylacetylide) complexes" @default.
• W2073527547 cites W1964603841 @default.
• W2073527547 cites W1966182479 @default.
• W2073527547 cites W1971275758 @default.
• W2073527547 cites W1971716460 @default.
• W2073527547 cites W1972798243 @default.
• W2073527547 cites W1985811692 @default.
• W2073527547 cites W1986503526 @default.
• W2073527547 cites W1986748514 @default.
• W2073527547 cites W1987702006 @default.
• W2073527547 cites W1989854295 @default.
• W2073527547 cites W1993592008 @default.
• W2073527547 cites W1993937590 @default.
• W2073527547 cites W1994401491 @default.
• W2073527547 cites W1995016599 @default.
• W2073527547 cites W1998849920 @default.
• W2073527547 cites W2001993329 @default.
• W2073527547 cites W2005286482 @default.
• W2073527547 cites W2007041987 @default.
• W2073527547 cites W2012962061 @default.
• W2073527547 cites W2013440762 @default.
• W2073527547 cites W2015024376 @default.
• W2073527547 cites W2020895640 @default.
• W2073527547 cites W2020903311 @default.
• W2073527547 cites W2022999752 @default.
• W2073527547 cites W2023271753 @default.
• W2073527547 cites W2024071116 @default.
• W2073527547 cites W2030946130 @default.
• W2073527547 cites W2031516077 @default.
• W2073527547 cites W2033990154 @default.
• W2073527547 cites W2039559098 @default.
• W2073527547 cites W2040337104 @default.
• W2073527547 cites W2042145666 @default.
• W2073527547 cites W2044346623 @default.
• W2073527547 cites W2044490585 @default.
• W2073527547 cites W2047724353 @default.
• W2073527547 cites W2050606126 @default.
• W2073527547 cites W2056967289 @default.
• W2073527547 cites W2058574018 @default.
• W2073527547 cites W2062109666 @default.
• W2073527547 cites W2062852634 @default.
• W2073527547 cites W2068617439 @default.
• W2073527547 cites W2074521835 @default.
• W2073527547 cites W2078745797 @default.
• W2073527547 cites W2080177771 @default.
• W2073527547 cites W2082396573 @default.
• W2073527547 cites W2088665773 @default.
• W2073527547 cites W2094642658 @default.
• W2073527547 cites W2100773105 @default.
• W2073527547 cites W2106911911 @default.
• W2073527547 cites W2107626891 @default.
• W2073527547 cites W2111091421 @default.
• W2073527547 cites W2128877508 @default.
• W2073527547 cites W2143981217 @default.
• W2073527547 cites W2164318957 @default.
• W2073527547 cites W2165806778 @default.
• W2073527547 cites W2318435639 @default.
• W2073527547 doi "https://doi.org/10.1039/c2dt32153j" @default.
• W2073527547 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23338679" @default.
• W2073527547 hasPublicationYear "2013" @default.
• W2073527547 type Work @default.
• W2073527547 sameAs 2073527547 @default.
• W2073527547 citedByCount "34" @default.
• W2073527547 countsByYear W20735275472013 @default.
• W2073527547 countsByYear W20735275472014 @default.
• W2073527547 countsByYear W20735275472015 @default.
• W2073527547 countsByYear W20735275472016 @default.
• W2073527547 countsByYear W20735275472017 @default.
• W2073527547 countsByYear W20735275472018 @default.
• W2073527547 countsByYear W20735275472019 @default.
• W2073527547 countsByYear W20735275472020 @default.
• W2073527547 countsByYear W20735275472022 @default.
• W2073527547 countsByYear W20735275472023 @default.
• W2073527547 crossrefType "journal-article" @default.
• W2073527547 hasAuthorship W2073527547A5019365638 @default.
• W2073527547 hasAuthorship W2073527547A5043270824 @default.
• W2073527547 hasAuthorship W2073527547A5057105243 @default.
• W2073527547 hasAuthorship W2073527547A5071822893 @default.
• W2073527547 hasAuthorship W2073527547A5087381063 @default.
• W2073527547 hasConcept C116569031 @default.
• W2073527547 hasConcept C119824511 @default.
• W2073527547 hasConcept C121332964 @default.
• W2073527547 hasConcept C125287762 @default.
• W2073527547 hasConcept C147597530 @default.
• W2073527547 hasConcept C152365726 @default.
• W2073527547 hasConcept C159985019 @default.
• W2073527547 hasConcept C170493617 @default.
• W2073527547 hasConcept C178790620 @default.
• W2073527547 hasConcept C181500209 @default.

• next