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- W2073532492 abstract "Abstract The study concerns the analysis of the four reduction waves obtained in a polarogram of Mo(VI) in 0.1 M aqueous sulfuric acid solution. Auxiliary experiments of controlled potential coulometric electrolysis and spectroscopic analysis of the reaction products show the first, the second and the third wave to be due to the reduction of Mo(VI) to Mo(V) and the fourth to Mo(V) to Mo(III). The first one is adsorptive in character and the third is enhanced catalytically in the presence of nitrate ion. These results are interpreted in terms of the respective reduction of the different kinds of Mo(VI) species coexisting in the solution. The development of catalytic current in the third wave indicates that only one type of Mo(V) species formed on the electrode must be active." @default.
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- W2073532492 date "1982-01-01" @default.
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- W2073532492 title "Polarographic study of Mo(VI) in aqueous sulfuric acid solutions" @default.
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- W2073532492 doi "https://doi.org/10.1016/0022-0728(82)85017-1" @default.
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