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- W2073534106 abstract "A series of semi-rigid analogues of the hormone 1α,25-dihydroxyvitamin D3 have been designed in order to study the topology required for binding to the hormone receptor (VDR). The new vitamin D3 analogues 2–5 possess a rigid C17C20 bond and minimal structural modifications on the side-chain with respect to the hormone. Key steps for the introduction of the side-chains of the new analogues 2–5 from hydrindanone 6 involve a stereoselective Wittig reaction, olefin isomerization and dihalocyclopropanation." @default.
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- W2073534106 date "1998-06-01" @default.
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- W2073534106 title "Design and synthesis of 1α,25-dihydroxyvitamin D3 analogues with fixed torsion angle C(16-17-20-22)" @default.
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- W2073534106 doi "https://doi.org/10.1016/s0040-4039(98)00867-3" @default.
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