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- W2073545820 abstract "We report the synthesis of a Fe-porphyrin-like carbon nanotube from conventional plasma-enhanced chemical vapor deposition. Covalent but seamless incorporation of the 5-6-5-6 porphyrinic $mathrm{Fe}mathrm{text{ensuremath{-}}}{mathrm{N}}_{4}$ moiety into the graphene hexagonal side wall was elucidated by x-ray and ultraviolet photoemission spectroscopies and first-principles electronic structure calculations. The resulting biomimetic nanotube exhibits an excellent oxygen reduction catalytic activity with the extreme structural stability over $0.1ifmmodetimeselsetexttimesfi{}{10}^{6}$ cycles, vastly superior to the commercial Pt-C catalyst." @default.
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- W2073545820 date "2011-04-28" @default.
- W2073545820 modified "2023-10-01" @default.
- W2073545820 title "Theory, Synthesis, and Oxygen Reduction Catalysis of Fe-Porphyrin-Like Carbon Nanotube" @default.
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- W2073545820 doi "https://doi.org/10.1103/physrevlett.106.175502" @default.
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