Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073549484> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2073549484 endingPage "3571" @default.
- W2073549484 startingPage "3559" @default.
- W2073549484 abstract "Abstract The reactions of various rhenium(III) precursers with the tetradentate umbrella ligand tris-(ortho-mercaptophenyl)phosphine (PS3 for the tri-anionic form) followed by various neutral donor ligands is the focus of this work. The addition of a solution of P(SLi)3 in THF to [ReBr3(THT)3] in THF followed by the addition of excess isonitrile gives the octahedral complex [PS3Re(CNiPr)2]. This reaction also allows isolation of [PS3Re(CNiPr)] which is separated from the bis-isonitrile complex via column chromatography. Both of these complexes were structurally characterized with the five-coordinate species displaying trigonal bipyramidal geometry and the six-coordinate species displaying a distorted octahedral geometry. The decomposition product [(S2PS-SPS2)Re] is also isolated from the chromatographic separation of the two isonitrile complexes. This neutral octahedral complex displays coordination through two phosphine and four thiolate moieties, with a non-coordinated disulfide bridge that links the remaining sulfurs. The addition of a solution of H3PS3 and iPr2NEt in THF to [ReBr3(THT)3] followed by the addition of dimethylphenylphosphine yields [PS3Re(PMe2Ph)2]. This complex, similar to the bis-isonitrile species, displays a distorted octahedral geometry. These complexes and others in the series have been fully characterized with NMR spectroscopy, infrared and mass spectrometry and elemental analyses." @default.
- W2073549484 created "2016-06-24" @default.
- W2073549484 creator A5006329797 @default.
- W2073549484 creator A5013393867 @default.
- W2073549484 creator A5038784656 @default.
- W2073549484 creator A5044071208 @default.
- W2073549484 creator A5068944189 @default.
- W2073549484 date "2005-09-01" @default.
- W2073549484 modified "2023-09-27" @default.
- W2073549484 title "Tris-mercaptophenylphosphine complexes of rhenium: Synthesis, reactivity and structural characterization" @default.
- W2073549484 cites W1967900554 @default.
- W2073549484 cites W1968768423 @default.
- W2073549484 cites W1978509337 @default.
- W2073549484 cites W1985240519 @default.
- W2073549484 cites W1991945739 @default.
- W2073549484 cites W1992590478 @default.
- W2073549484 cites W2001132271 @default.
- W2073549484 cites W2005098392 @default.
- W2073549484 cites W2008087651 @default.
- W2073549484 cites W2020239880 @default.
- W2073549484 cites W2028794757 @default.
- W2073549484 cites W2034526641 @default.
- W2073549484 cites W2044295878 @default.
- W2073549484 cites W2065488834 @default.
- W2073549484 cites W2067093231 @default.
- W2073549484 cites W2073783906 @default.
- W2073549484 cites W2089538505 @default.
- W2073549484 cites W2134655897 @default.
- W2073549484 cites W2155877380 @default.
- W2073549484 cites W2319978776 @default.
- W2073549484 doi "https://doi.org/10.1016/j.ica.2004.09.065" @default.
- W2073549484 hasPublicationYear "2005" @default.
- W2073549484 type Work @default.
- W2073549484 sameAs 2073549484 @default.
- W2073549484 citedByCount "8" @default.
- W2073549484 countsByYear W20735494842012 @default.
- W2073549484 countsByYear W20735494842013 @default.
- W2073549484 countsByYear W20735494842015 @default.
- W2073549484 countsByYear W20735494842021 @default.
- W2073549484 countsByYear W20735494842022 @default.
- W2073549484 crossrefType "journal-article" @default.
- W2073549484 hasAuthorship W2073549484A5006329797 @default.
- W2073549484 hasAuthorship W2073549484A5013393867 @default.
- W2073549484 hasAuthorship W2073549484A5038784656 @default.
- W2073549484 hasAuthorship W2073549484A5044071208 @default.
- W2073549484 hasAuthorship W2073549484A5068944189 @default.
- W2073549484 hasConcept C142724271 @default.
- W2073549484 hasConcept C171250308 @default.
- W2073549484 hasConcept C178790620 @default.
- W2073549484 hasConcept C185592680 @default.
- W2073549484 hasConcept C192562407 @default.
- W2073549484 hasConcept C204787440 @default.
- W2073549484 hasConcept C21951064 @default.
- W2073549484 hasConcept C2776910235 @default.
- W2073549484 hasConcept C2780841128 @default.
- W2073549484 hasConcept C2781014771 @default.
- W2073549484 hasConcept C505216180 @default.
- W2073549484 hasConcept C55493867 @default.
- W2073549484 hasConcept C71240020 @default.
- W2073549484 hasConcept C71924100 @default.
- W2073549484 hasConceptScore W2073549484C142724271 @default.
- W2073549484 hasConceptScore W2073549484C171250308 @default.
- W2073549484 hasConceptScore W2073549484C178790620 @default.
- W2073549484 hasConceptScore W2073549484C185592680 @default.
- W2073549484 hasConceptScore W2073549484C192562407 @default.
- W2073549484 hasConceptScore W2073549484C204787440 @default.
- W2073549484 hasConceptScore W2073549484C21951064 @default.
- W2073549484 hasConceptScore W2073549484C2776910235 @default.
- W2073549484 hasConceptScore W2073549484C2780841128 @default.
- W2073549484 hasConceptScore W2073549484C2781014771 @default.
- W2073549484 hasConceptScore W2073549484C505216180 @default.
- W2073549484 hasConceptScore W2073549484C55493867 @default.
- W2073549484 hasConceptScore W2073549484C71240020 @default.
- W2073549484 hasConceptScore W2073549484C71924100 @default.
- W2073549484 hasIssue "13" @default.
- W2073549484 hasLocation W20735494841 @default.
- W2073549484 hasOpenAccess W2073549484 @default.
- W2073549484 hasPrimaryLocation W20735494841 @default.
- W2073549484 hasRelatedWork W1976952039 @default.
- W2073549484 hasRelatedWork W2048471262 @default.
- W2073549484 hasRelatedWork W2062475052 @default.
- W2073549484 hasRelatedWork W2073549484 @default.
- W2073549484 hasRelatedWork W2079638180 @default.
- W2073549484 hasRelatedWork W2264042629 @default.
- W2073549484 hasRelatedWork W2398661445 @default.
- W2073549484 hasRelatedWork W3008718849 @default.
- W2073549484 hasRelatedWork W3047932790 @default.
- W2073549484 hasRelatedWork W3193590266 @default.
- W2073549484 hasVolume "358" @default.
- W2073549484 isParatext "false" @default.
- W2073549484 isRetracted "false" @default.
- W2073549484 magId "2073549484" @default.
- W2073549484 workType "article" @default.