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- W2073567478 abstract "Carbene compounds of the Group VI metals, (CO)5MC(X)C6H4Y in which M=Cr, Mo, W; X=OMe, NCnH2n (n=2, 4) and Y=p-OMe, p-Me, H, p-Cl, react with triorganoelement hydrides of the Group IV elements, R3EH, in which R=alkyl, Ph and E=Si, Ge, Sn, in the presence of a coordinating base (pyridine, acetonitrile) in hexane solution to give compounds of the type R3ECHXC6H4Y whose characterisation is reported. Competition experiments are used to show that the susceptibility of R3EH to insertion of the fragment [PhCOMe] varies in the order Et3SiH > Ph3SiH < Ph3GeH < Ph3SnH, Pr3SnH. The formation of Ph3SiOMe in the reaction of Ph3SiH with the complexes (CO)5CrC(OMe)C6H4Y is discussed." @default.
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- W2073567478 date "1973-07-01" @default.
- W2073567478 modified "2023-09-26" @default.
- W2073567478 title "The reaction between transition metal carbene complexes and organometallic hydrides. A simple route to α-alkoxy and α-dialkylamino benzyl compounds of silicon, germanium and tin" @default.
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- W2073567478 doi "https://doi.org/10.1016/s0022-328x(00)84042-5" @default.
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