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• W2073569483 abstract "The structure of inhomogeneous systemshard sphere near a planar hard wall and hard sphere in a porewas studied employing the formula for the background correlation function in terms of the residual chemical potentials of hard spheres and that of a hard dumbbell (or a combined body). The enlarged hard dumbbell is considered for determination of the basic geometric quantities: volume, surface area, and mean radius (the mean curvature integral divided by 4π for convex bodies). A novel method to determine the mean radius is proposed. Detailed discussion of the way of determining the single geometric quantities in special cases of systems (hard sphere + hard wall) and (hard sphere + spherical pore) is given. The predicted density profiles or distribution functions compare well with pseudoexperimental data in the range of the reduced distances x ≤ 2." @default.
• W2073569483 created "2016-06-24" @default.
• W2073569483 creator A5029737875 @default.
• W2073569483 date "2007-07-19" @default.
• W2073569483 modified "2023-09-25" @default.
• W2073569483 title "Structure of Hard Spheres near a Hard Wall and in a Pore from the Residual Chemical Potential" @default.
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• W2073569483 doi "https://doi.org/10.1021/jp0723362" @default.
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