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- W2073573213 abstract "Abstract A high‐yielding alternative synthesis of the dppm‐bridged heteronuclear cluster RuOs 3 (μ‐H) 2 (CO) 9 (μ‐CO) 2 (μ‐dppm) ( 1 ) [dppm = bis(diphenylphosphanyl)methane] has been developed. Thermolysis of 1 resulted in dephenylation of both phosphane groups to afford the butterfly cluster RuOs 3 (CO) 12 (μ 4 ,κ 2 :κ 2 ‐PhPCH 2 PPh) ( 2 ). The reaction of 1 with selected alkynes afforded the products RuOs 3 (μ‐H)(CO) 8 (μ‐CO)(μ 3 ,κ 2 :κ 1 ‐PhPCH 2 PPh 2 )(μ 3 ,η 1 :η 2 :η 1 ‐L) ( 3 ) (L = alkyne) in which the alkyne is aligned parallel to an Os–Os bond(// Os‐Os isomer). The clusters incorporating internal alkynes underwent isomerization to the //Ru‐Os isomer by alkyne and hydride migration. Several other cluster products of these reactions were also identified, including RuOs 3 (μ‐H)(CO) 8 (μ‐CO)(μ 3 ,κ 2 :κ 1 ‐PhPCH 2 PPh 2 )(μ 3 ,η 1 :η 2 :η 1 ‐ t BuC 2 CHO)( 6 ) in which the methyl group of the alkyne has been oxidized to an aldehyde. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W2073573213 created "2016-06-24" @default.
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- W2073573213 date "2007-03-27" @default.
- W2073573213 modified "2023-09-23" @default.
- W2073573213 title "The Ditertiary-Phosphane-Bridged Heteronuclear Cluster RuOs3(μ-H)2(CO)9(μ-CO)2(μ-dppm): Synthesis and Reactivity with Alkynes" @default.
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- W2073573213 doi "https://doi.org/10.1002/ejic.200601118" @default.
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