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• W2073596229 abstract "The known compounds N-(2,4-dinitrophenyl)-4,4′-bipyridinium (2,4-DNPhQ+), N-phenyl-4,4′-bipyridinium (PhQ+) and N-(4-acetylphenyl)-4,4′-bipyridinium (4-AcPhQ+) have been used to prepare a series of ruthenium complexes of the type [RuCl(CO)(PPh3)2(L)] (where, L = 2,4-DNPhQ+ or PhQ+ or 4-AcPhQ+). The latter complexes reacted with sulphur derivative to give [RuCl(CO)(PPh3)2(L)(L′)] (where, L′ = thio-9-xanthone). These new ruthenium complexes display intense, visible metal-to-ligand charge-transfer (MLCT) absorptions, due to dπ(Ru) → π*(pyridinium) excitations. The MLCT energy decreases as the acceptor strength increases in the order PhQ+ < 4-AcPhQ+ < 2,4-DNPhQ+. The new ruthenium complexes have been characterized by using standard analytical and spectroscopic techniques. Fluorescence and antibacterial activity of the ligands and appropriate complexes has also been carried out." @default.
• W2073596229 created "2016-06-24" @default.
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• W2073596229 date "2010-07-01" @default.
• W2073596229 modified "2023-10-18" @default.
• W2073596229 title "Antibacterial and luminescent properties of new donor–acceptor ruthenium triphenylphosphine–bipyridinium complexes" @default.
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• W2073596229 doi "https://doi.org/10.1016/j.microc.2009.12.006" @default.
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