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- W2073602246 abstract "The ionization and fragmentation of dimethyl and diethyl ether have been studied by means of photoionization at room temperature and low temperature. The parent ion thresholds show evidence of hot band effects, and the adiabatic ionization potentials have been determined to be 10.01 ± 0.01 eV for dimethyl ether and 9.60 ± 0.01 eV for diethyl ether. The temperature dependence of thresholds for the primary fragmentation processes in both molecules can be accounted for by rotational and vibrational hot band effects. Heats of formation at absolute zero have been obtained for the species CH3OCH2+, CH3CH2O = CHCH3+ and CH2 = OCH2CH3+. Evidence is obtained for important contributions of autoionization to ionization and fragmentation at higher energies." @default.
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- W2073602246 date "1977-09-01" @default.
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- W2073602246 title "Photoionization of dimethyl ether and diethyl ether" @default.
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- W2073602246 doi "https://doi.org/10.1016/0020-7381(77)80100-9" @default.
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