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• W2073608505 startingPage "61" @default.
• W2073608505 abstract "The diamagnetic complexes (n-Bu4N)4[PM11O39{Mo(NO)}] (M = Mo, W) have been synthesized in acetonitrile by reaction of the lacunary [PM11O39]7− species, generated in situ through degradation of the patent complete Keggin anions by n-Bu4NOH, with either (n-Bu4N)2[Mo5O13(OMe)4(NO){Na(MeOH)}]·3MeOH or [Mo(NO)(OMe)(Me2CNO)2]2 acting as a source of the [Mo(NO)]3+ unit. These new nitrosyl-oxometalates have been characterized by elemental analysis, infrared spectroscopy, electrochemistry, and 31P and 183W spectroscopy. Comparison of electrochemical and spectral data of the nitrosyl derivatives to those of the parent Keggin anions demonstrate that the electron-withdrawing effect of the nitrosyl ligand is opposed to the overall increase in charge of the heteropolymetalate framework arising from the replacement of an MO4+ unit by an [Mo(NO)]3+ unit. In the case of [PW11O39{Mo(NO)}]4−, 183W NMR data also support some delocalization of the Mo(II) d-electrons onto the polytungstate ligand." @default.
• W2073608505 created "2016-06-24" @default.
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• W2073608505 date "1994-01-01" @default.
• W2073608505 modified "2023-10-16" @default.
• W2073608505 title "Synthesis and characterization of Keggin derivatives containing an [Mo(NO)]3+ unit: (n-Bu4N)4[PM11O39{Mo(NO)}] (M  Mo, W)" @default.
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• W2073608505 doi "https://doi.org/10.1016/0020-1693(93)03666-x" @default.
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