FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2073619962> ?p ?o ?g. }

• W2073619962 endingPage "12609" @default.
• W2073619962 startingPage "12601" @default.
• W2073619962 abstract "The quenching of triplet C60 by phenols is greatly enhanced by addition of pyridines, which also lower the phenol voltammetric oxidation potentials. Flash photolysis shows that the products of this quenching reaction are the C60•- anion radical, neutral phenoxy (or naphthoxy) radicals, and protonated pyridines. Analysis of the second-order kinetics gives quenching rate constants and values of formation constants of hydrogen-bonded phenol−pyridine pairs. The latter agree with those derived from absorption spectra over a wide range of phenols, pyridines, and solvents. Significant deuterium kinetic isotope effects are observed, indicating the importance of both proton transfer and hydrogen bonding in enhancing the rate. Quenching rates and radical yields both increase with solvent polarity. It is concluded that this quenching process involves interaction between 3C60 and a hydrogen-bonded phenol−pyridine complex, in which electron transfer from the phenol to 3C60 is concerted with proton transfer from phenol to hydrogen-bonded pyridine." @default.
• W2073619962 created "2016-06-24" @default.
• W2073619962 creator A5003386382 @default.
• W2073619962 creator A5018018548 @default.
• W2073619962 creator A5042831122 @default.
• W2073619962 date "1997-12-01" @default.
• W2073619962 modified "2023-10-15" @default.
• W2073619962 title "Coupled Electron-Proton Transfer in Interactions of Triplet C₆₀ with Hydrogen-Bonded Phenols: Effects of Solvation, Deuteration, and Redox Potentials" @default.
• W2073619962 cites W12334191 @default.
• W2073619962 cites W1560725155 @default.
• W2073619962 cites W1603399366 @default.
• W2073619962 cites W1965026731 @default.
• W2073619962 cites W1971438831 @default.
• W2073619962 cites W1971911697 @default.
• W2073619962 cites W1978669634 @default.
• W2073619962 cites W1978754056 @default.
• W2073619962 cites W1981677371 @default.
• W2073619962 cites W1981849326 @default.
• W2073619962 cites W1988911622 @default.
• W2073619962 cites W1993629090 @default.
• W2073619962 cites W2012798961 @default.
• W2073619962 cites W2015120301 @default.
• W2073619962 cites W2024678031 @default.
• W2073619962 cites W2032085721 @default.
• W2073619962 cites W2036773769 @default.
• W2073619962 cites W2041540545 @default.
• W2073619962 cites W2046024796 @default.
• W2073619962 cites W2048173493 @default.
• W2073619962 cites W2051053753 @default.
• W2073619962 cites W2053645092 @default.
• W2073619962 cites W2054644541 @default.
• W2073619962 cites W2056591540 @default.
• W2073619962 cites W2060020632 @default.
• W2073619962 cites W2068226906 @default.
• W2073619962 cites W2078874694 @default.
• W2073619962 cites W2082428959 @default.
• W2073619962 cites W2138723916 @default.
• W2073619962 cites W2317538821 @default.
• W2073619962 cites W2624207816 @default.
• W2073619962 cites W2950845835 @default.
• W2073619962 cites W2953279044 @default.
• W2073619962 doi "https://doi.org/10.1021/ja9727528" @default.
• W2073619962 hasPublicationYear "1997" @default.
• W2073619962 type Work @default.
• W2073619962 sameAs 2073619962 @default.
• W2073619962 citedByCount "96" @default.
• W2073619962 countsByYear W20736199622012 @default.
• W2073619962 countsByYear W20736199622013 @default.
• W2073619962 countsByYear W20736199622014 @default.
• W2073619962 countsByYear W20736199622015 @default.
• W2073619962 countsByYear W20736199622016 @default.
• W2073619962 countsByYear W20736199622017 @default.
• W2073619962 countsByYear W20736199622018 @default.
• W2073619962 countsByYear W20736199622019 @default.
• W2073619962 countsByYear W20736199622020 @default.
• W2073619962 countsByYear W20736199622021 @default.
• W2073619962 countsByYear W20736199622022 @default.
• W2073619962 countsByYear W20736199622023 @default.
• W2073619962 crossrefType "journal-article" @default.
• W2073619962 hasAuthorship W2073619962A5003386382 @default.
• W2073619962 hasAuthorship W2073619962A5018018548 @default.
• W2073619962 hasAuthorship W2073619962A5042831122 @default.
• W2073619962 hasConcept C110010208 @default.
• W2073619962 hasConcept C121332964 @default.
• W2073619962 hasConcept C121745418 @default.
• W2073619962 hasConcept C123669783 @default.
• W2073619962 hasConcept C13472781 @default.
• W2073619962 hasConcept C145148216 @default.
• W2073619962 hasConcept C148093993 @default.
• W2073619962 hasConcept C148898269 @default.
• W2073619962 hasConcept C178790620 @default.
• W2073619962 hasConcept C185592680 @default.
• W2073619962 hasConcept C2777702071 @default.
• W2073619962 hasConcept C2779485729 @default.
• W2073619962 hasConcept C2780471494 @default.
• W2073619962 hasConcept C30095370 @default.
• W2073619962 hasConcept C58364064 @default.
• W2073619962 hasConcept C62520636 @default.
• W2073619962 hasConcept C69928629 @default.
• W2073619962 hasConcept C75473681 @default.
• W2073619962 hasConcept C91881484 @default.
• W2073619962 hasConcept C93391505 @default.
• W2073619962 hasConceptScore W2073619962C110010208 @default.
• W2073619962 hasConceptScore W2073619962C121332964 @default.
• W2073619962 hasConceptScore W2073619962C121745418 @default.
• W2073619962 hasConceptScore W2073619962C123669783 @default.
• W2073619962 hasConceptScore W2073619962C13472781 @default.
• W2073619962 hasConceptScore W2073619962C145148216 @default.
• W2073619962 hasConceptScore W2073619962C148093993 @default.
• W2073619962 hasConceptScore W2073619962C148898269 @default.
• W2073619962 hasConceptScore W2073619962C178790620 @default.
• W2073619962 hasConceptScore W2073619962C185592680 @default.
• W2073619962 hasConceptScore W2073619962C2777702071 @default.
• W2073619962 hasConceptScore W2073619962C2779485729 @default.
• W2073619962 hasConceptScore W2073619962C2780471494 @default.
• W2073619962 hasConceptScore W2073619962C30095370 @default.
• W2073619962 hasConceptScore W2073619962C58364064 @default.
• W2073619962 hasConceptScore W2073619962C62520636 @default.

• next