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- W2073622438 abstract "The effect of hydrostatic pressure up to 120MPa on the stability boudaries of crystalline phases and phase transition behaviour observed in MSiF6·6H2O (M = Fe, Co, Ni) in the temperature range 20–300 K, is studied by X-ray diffractometry and the differential thermal analysis technique. Existence of critical pressures and the destabilization of the low-temperature monoclinic phase in FeSiF6·6H2O and CoSiF6·6H2O are established. P-T diagrams of the investigated fluosilicate hexahydrates showing the unique variety of phases and phase transitions are plotted. It is shown that the P-T phase diagram of crystalline states NiSiF6·6H2O has the same form as the diagram region CoSiF6·6H2O corresponding to pressures which exceed the critical pressure for the stability of the monoclinic phase." @default.
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- W2073622438 date "1992-10-01" @default.
- W2073622438 modified "2023-10-05" @default.
- W2073622438 title "Behaviour of iron, cobalt and nickel fluosilicate hehahydrates under pressure" @default.
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- W2073622438 doi "https://doi.org/10.1016/0921-4526(92)90561-6" @default.
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